Investigating the synergistic effects of various amine groups on Zeolite-Y for CO capture.

Growing concern about global warming and greenhouse effects has led to persistent demands for increased energy efficiency and reduced carbon dioxide emissions. As a result, energy-intensive processing of carbon dioxide separation became imperative. Accordingly, energy-efficient, economically viable carbon dioxide separation technologies are sought as carbon dioxide capture options for future industrial process schemes. The article provides an overview of current technology for the separation of carbon dioxide, specifically focusing on adsorption. In this study, amine-loaded Zeolite-Y adsorbents were evaluated to enhance carbon dioxide adsorption capacity through synthesis, characterization, and the adsorption of carbon dioxide, within the context of current trends in separation technology. This study aims to study the ability of amine-loaded Zeolite-Y to adsorb carbon dioxide using three different loadings ethanolamine, diethanolamine, and triethanolamine. The amine-loaded materials were characterized by various technologies, including X-ray diffraction pattern (XRD), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), Brunauer-Emmett-Teller (BET), and field emission scanning electron microscope (FESEM) studies. The study suggests that monoethanolamine-loaded Zeolite-Y is a promising and cost-effective adsorbent for carbon dioxide adsorption in comparison to other synthesized amine-loaded adsorbents. The adsorbent has been able to adsorb carbon dioxide in the range of 1.14-2.26 mmol g at 303 K and 1 bar for a loading of 1, 5, and 10 wt.% amine groups.