Current Induced Spin-Polarization in Chiral Molecules.

J Phys Chem Lett

Clore Laboratory, University of Buckingham, Buckingham MK18 1EG, U.K.

Published: June 2024

The inverse spin-galvanic effect or current-induced spin-polarization is mainly associated with interfaces between different layers in semiconducting heterostructures, surfaces of metals, and bulk semiconducting materials. Here, we theoretically predict that the inverse spin-galvanic effect should also be present in chiral molecules, as a result of the chiral induced spin selectivity effect. As proof-of-principle, we calculate the nonequilibrium properties of a model system that previously has been successfully used to explain a multitude of aspects related to the chiral induced spin selectivity effect. Here we show that current driven spin-polarization in a chiral molecule gives rise to a magnetic moment that is sensitive to external magnet field. The chiral molecule then behaves like a soft ferromagnet. This, in turn, suggests that magnetic permeability measurement in otherwise nonmagnetic systems may be used noninvasively to detect the presence of spin-polarized currents.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11194818PMC
http://dx.doi.org/10.1021/acs.jpclett.4c01362DOI Listing

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