Chaos
Department of Physics and Astronomy, George Mason University, Fairfax, Virginia 22030, USA.
Published: June 2024
We present and demonstrate a method to produce quantitative and qualitative descriptions of transient dynamics from empirical data, with the purpose of analyzing a novel transient discovered in liquid crystal electroconvection. By constructing a tensor bundle around an exemplar transient and creating a chart at every step aligned with the direction of propagation, we show that the Jacobian estimation problem can be reduced by a single dimension, relaxing data requirements and clarifying results. We apply this analysis to identify the onset of a boundary crisis in a predator-prey model. The resulting tensor bundle estimated from image data taken during a dynamical phase transition in a nematic liquid crystal details the behavior of the system along that trajectory, allowing topological analysis. Using this method, we quantify a saddle point in the phase space that drives the initial dynamics during a sudden increase in the driving voltage.
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http://dx.doi.org/10.1063/5.0190107 | DOI Listing |
Int J Pharm
March 2025
The Casali Center for Applied Chemistry, The Institute of Chemistry, The Hebrew University of Jerusalem, Edmond J. Safra Campus, Jerusalem 9190401, Israel. Electronic address:
The present study introduces a novel formulation approach for utilizing Lyotropic Liquid Crystals (LLCs) as sustained oral delivery systems. For this purpose, we have developed a novel bottom-up fabrication process that enables the LLC beads to be formulated with precise control over their diameter by pre-determining their surface area. By directly controlling the effective diffusional interfacial surface of the LLCs, their release rate from the LLC beads can be determined.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2025
CAS Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
Blue-phase liquid crystals (BPLCs) have shown great potential in hyper-reflective display technology due to their narrow bandgap, high color saturation, and fast response characteristics. However, there remains a significant challenge for achieving open-patternable dual-chiral BPLC films (DH-BP) and precise tuning for efficient hyper-reflection due to the packaging limitations of liquid crystal cells and the complexities of the dynamic bandgap matching principle. In this study, an in situ secondary growth strategy was proposed to successfully fabricate structurally continuous and uniform DH-BP films.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
March 2025
The University of Texas at Austin, Chemistry, UNITED STATES OF AMERICA.
Mounting concerns regarding per-/poly-fluoroalkyl substances (PFAS) on human health are focusing attention on trace level PFAS detection in aqueous environments. Here we report a readily prepared small molecule, 2,6-bis(3,5-diethyl-1H-pyrrol-2-yl)pyridine (receptor 1), that displays high binding affinities (logKa = 4.9-6.
View Article and Find Full Text PDFPhys Chem Chem Phys
March 2025
Department of Chemistry, Rice University, Houston, TX 77005, USA.
Liquid crystals (LCs) combine the anisotropy of crystals with the fast molecular dynamics of liquids. Controlling the molecular orientation of LCs is the key enabling feature of liquid crystal displays (LCDs), a technology that has played a pivotal role in ushering in the digital age of today. Here we review controlling molecular organization in LCs over large distances for a different application: the assembly of macroscopically organized solids.
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