Two coordinate boron cations are rare. Herein we report the synthesis of [RNSiMeCH]BF (R = Dipp 3, 1-Ad 5) (Dipp = CH(iPr), Ad = CH) the reaction of BF with the corresponding dilithiated diamides. Subsequent abstraction of fluoride provided the corresponding borinium salts, [(RNSiMeCH)B][B(CF)] (R = Dipp 6, 1-Ad 8). While the former was generated, the latter proved isolable and was crystallographically characterized.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d4dt01242a | DOI Listing |
Publication Analysis
Top Keywords
dipp 1-ad
8
chelated borinium
4
borinium cation
4
cation coordinate
4
coordinate boron
4
boron cations
4
cations rare
4
rare report
4
report synthesis
4
synthesis [rnsimech]bf
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!