AI Article Synopsis
- The text provides an overview of magnetic circular dichroism (MCD) spectroscopy, focusing on both its experimental and theoretical aspects, along with a discussion on magnetic circularly polarized luminescence (MCPL).
- It highlights major research areas, particularly involving porphyrinoid systems, aggregates, materials, and organic molecules that aid in understanding MCD, especially in chiral systems and natural products with potential pharmaceutical applications.
- The discussion also includes the vibrational version of MCD, known as MVCD, which is recorded in the infrared spectrum, concluding with some insights on future directions in the field.
Article Abstract
A historical sketch of the MCD (magnetic circular dichroism) spectroscopy is reported in its experimental and theoretical aspects. MCPL (magnetic circularly polarized luminescence) is also considered. The main studies are presented encompassing porphyrinoid systems, aggregates and materials, as well as simple organic molecules useful for the advancement of the interpretation. The MCD of chiral systems is discussed with special attention to new studies of natural products with potential pharmaceutical valence, including Amaryllidaceae alkaloids and related isocarbostyrils. Finally, the vibrational form of MCD, called MVCD, which is recorded in the IR part of the spectrum is also discussed. A final brief note on perspectives is given.
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| http://dx.doi.org/10.1016/j.saa.2024.124583 | DOI Listing |
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