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Synthesis, crystal structure and properties of poly[di-μ-chlorido-di-μ-chlorido-bis-[4-methyl--(pyridin-2-yl-methyl-idene)aniline]dicadmium(II)]. | LitMetric

Synthesis, crystal structure and properties of poly[di-μ-chlorido-di-μ-chlorido-bis-[4-methyl--(pyridin-2-yl-methyl-idene)aniline]dicadmium(II)].

Acta Crystallogr E Crystallogr Commun

Thammasat University Research Unit in Multifunctional Crystalline Materials and Applications (TU-MCMA), Faculty of Science and Technology, Thammasat University, Pathum Thani 12121, Thailand.

Published: May 2024

AI Article Synopsis

Article Abstract

The title coordination polymer with the 4-methyl--(pyridin-2-yl-methyl-idene)aniline Schiff base ligand (, CHN), [CdCl(CHN)] (), exhibits a columnar structure extending parallel to [100]. The columns are aligned in parallel and are decorated with chelating ligands on both sides. They are elongated into a supra-molecular sheet extending parallel to (01) through π-π stacking inter-actions involving ligands of neighbouring columns. Adjacent sheets are packed into the tri-periodic supra-molecular network through weak C-H⋯Cl hydrogen-bonding inter-actions that involve the phenyl CH groups and chlorido ligands. The thermal stability and photoluminescent properties of () have also been examined.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11151312PMC
http://dx.doi.org/10.1107/S2056989024004274DOI Listing

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