Effect of counterions on the structure and dynamics of water near a negatively charged surfactant: a theoretical vibrational sum frequency generation study.

Charged aqueous interfaces are of paramount importance in electrochemical, biological and environmental sciences. The properties of aqueous interfaces with ionic surfactants can be influenced by the presence of counterions. Earlier experiments involving vibrational sum frequency generation (VSFG) spectroscopy of aqueous interfaces with negatively charged sodium dodecyl sulfate (NaDS or SDS) surfactants revealed that the hydrogen bonding strength of the interfacial water molecules follows a certain order when salts of monovalent and divalent cations are added. It is known that cations do not directly participate in hydrogen bonding with water molecules, rather they only influence the hydrogen bonded network through their electrostatic fields. In the current work, we have simulated the aqueous interfacial systems of sodium dodecyl sulfate in the presence of chloride salts of mono and divalent countercations. The electronic polarization effects on the ions are considered at a mean-field level within the electronic continuum correction model. Our calculations of the VSFG spectra show a blue shift in the presence of added countercations whose origin is traced to different relative contributions of water molecules from the solvation shells of the surfactant headgroups and the remaining water molecules in the presence of countercations. Furthermore, the cations shield the electric fields of the surfactant headgroups, which in turn influences the contributions of water molecules to the total VSFG spectrum. This shielding effect becomes more significant when divalent countercations are present. The dynamics of water molecules is found to be slower at the interface in comparison to the bulk. The interfacial depth dependence of various dynamical quantities shows that the interface is structurally and dynamically more heterogeneous at the microscopic level.