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| http://dx.doi.org/10.1515/medgen-2023-2063 | DOI Listing |
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Background: Despite extensive studies of the Mesozoic-Cenozoic magmatic history of Svalbard, little has been done on the Paleozoic magmatism due to fewer available outcrops.
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In the past few years, the direct activation of organohalides by ligated boryl radicals has emerged as a potential synthetic tool for cross-coupling reactions. In most existing methods, ligated boryl radicals are accessed from NHC-boranes or amine-boranes. In this work, we report a new photocatalytic platform by modular assembly of readily available amines and diboron esters to access a library of ligated boryl radicals for reaction screening, thus enabling the cross-coupling of organohalides and alkenes including both activated and unactivated ones for C(sp)-C(sp) bond formation by using the assembly of DABCO A1 and BNepB1.
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The efficient harvesting of triplet excitons is key to realizing high efficiency blue fluorescent organic light-emitting diodes (OLEDs). Triplet-triplet annihilation (TTA) up-conversion is one of the effective triplet-harvesting strategies. However, during the TTA up-conversion process, a high current density is necessary due to the competitive non-radiative triplet losses.
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