In light of the limitations of the current piezoelectric energy harvesters and the demand for self-power supply in wireless sensor nodes, a novel positive feedback piezoelectric energy harvester based on nonlinear magnetic coupling is proposed. The operational characteristics of this energy harvester are investigated from three perspectives: theory, simulation, and experiment. First, a nonlinear electromechanical coupling mathematical model that describes the dynamic response of the energy harvester system is established by combining the Hamilton variational principle with the piezoelectric theory. This provides a theoretical foundation for subsequent research. Second, finite element method simulations are employed to optimize the structural parameters of the energy harvester and study the impact of nonlinear magnetic force on its output performance. Finally, an experimental prototype is fabricated and an experimental test system is constructed to validate the designed positive feedback piezoelectric energy harvester. The results demonstrate that changes in the longitudinal beam angle have minimal effect on energy capture efficiency. By appropriately increasing the bending surface length, reducing initial magnetic moment, and augmenting mass block weight, wider working frequency bands and higher power generation capacity can be achieved when vibrating in low-energy orbits. The experimental findings align closely with theoretical design values and contribute to advancing broadband multi-directional piezoelectric energy harvesting technology in order to provide high-performance vibration-based power solutions for wireless applications.
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http://dx.doi.org/10.1063/5.0206110 | DOI Listing |
J Phys Chem A
January 2025
College of Physics Science and Technology, Yangzhou University, Yangzhou 225009, China.
Developing high-performance solar cells is a practical way to improve clean energy conversion efficiency. However, the performance of solar cells faces challenges such as fast carrier combination, poor stability, and limited solar light harvesting. Herein, we propose a strategy by decorating periodic holes in two-dimensional (2D) porous carbon-nitrogen (CN) materials with a zero-dimensional (0D) semiconducting (ZnO) cluster.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Laboratory of Advanced Computation and Theory for Materials and Chemistry, Department of Chemistry, National Institute of Technology Warangal (NITW), Warangal, Telangana 506004, India.
We report nonconjugated monocyclic dienes (nCMDs) as unique photoswitchable molecules that hold promise for harvesting substantial solar energy and storing it for extended durations. Herein, cyclohepta-1,4-diene and its N-heterocyclic analogue have been considered as prototypical models for investigating photoswitching behavior in nCMDs. Initially, the nonradiative deactivation pathway of nCMD from the low-lying excited state to the [2 + 2]-cycloadduct has been evaluated.
View Article and Find Full Text PDFFront Chem
January 2025
Nanophotonics Laboratory, Department of Physics, Bharathidasan University, Tiruchirappalli, India.
An interesting approach of including an upconverter in the MoS counter electrode can yield broadband light harvesting Pt-free DSSC assembly. Here different upconverter (UC) nanoparticles (Yb, Er incorporated NaYF, YF, CeO & YO) were synthesized and loaded in MoS thin film by hydrothermal method. The inclusion of UCs in MoS films exposed without any secondary formation of upconverters and the uniform deposition of the films are confirmed through XRD and FESEM analysis respectively.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Environmental Engineering, Kwangwoon University, Seoul 01897, Republic of Korea.
The advancement of highly efficient and cost-effective electrocatalysts for electrochemical water splitting, along with the development of triboelectric nanogenerators (TENGs), is crucial for sustainable energy generation and harvesting. In this study, a novel hybrid composite by integrating graphitic carbon nitride (GCN) with an earth-abundant FeMg-layered double hydroxide (LDH) (GCN@FeMg-LDH) was synthesized by the hydrothermal approach. Under controlled conditions, with optimized concentrations of metal ions and GCN, the fabricated electrode, GCN@FeMg-LDH demonstrated remarkably low overpotentials of 0.
View Article and Find Full Text PDFJ Chem Phys
January 2025
Department of Chemical Engineering, Indian Institute of Science, Bengaluru, Karnataka 560012, India.
Heteropolar two-dimensional materials, including hexagonal boron nitride (hBN), are promising candidates for seawater desalination and osmotic power harvesting, but previous simulation studies have considered bare, unterminated nanopores in molecular dynamics (MD) simulations. There is presently a lack of force fields to describe functionalized nanoporous hBN in aqueous media. To address this gap, we conduct density functional theory (DFT)-based ab initio MD simulations of hBN nanopores surrounded by water molecules.
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