Fluorescence sensing of water in various organic solvents based on a novel cyclic polymer.

Spectrochim Acta A Mol Biomol Spectrosc

Tianjin Key Laboratory of Multiplexed Identification for Port Hazardous Chemicals, College of Science, College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, China. Electronic address:

Published: October 2024

A sensor capable of sensing of water in various organic solvents ranging from water-soluble to water-miscible solvents is still a challenging task. In this research, a cyclic polymer fluorescence chemosensor (CPFC) has been developed for sensing of water by turn-on model in 9 organic solvents and turn-off model in DMA, where the broadest concentration range and the lowest detection limit was obtained for water in DMA (10 %-90 %) and dioxane (0.011 %), respectively. The sensing mechanism is explored by theory calculation and experimental investigation. The amphiphilic nature endows the polymer probe with great potential for measuring various contaminants from aqueous and nonaqueous mediums. Furthermore, the present search highlights the potential applications of cyclic polymer as fluorescence probes in the field of sensing.

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http://dx.doi.org/10.1016/j.saa.2024.124554DOI Listing

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