The present study concerns the electrochemical treatment between steel embedment and an external mesh in mitigating OH ion leaching from the cement paste into external water, which was ensured by a microscopic observation on the surface of the cement paste specimen at the backscattered electron (BSE) image analysis and by measuring the leaching rate for OH ions with time. The electrochemical properties for the treatment included 1000 mA/m current density and 4 weeks duration. As a result, the pH at the electrochemical treatment in the external water accounted for 9.32 in the pH, while the untreated specimen indicated 13.46, implying a quite reduction of OH ion leaching to a water environment. The porosity on the surface was reduced to lower the access of external water, while the decomposition of C-S-H gel was lowered. Due to the precipitation of Ca(OH), a further solidification of hydration phases could lower OH ion leaching.
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http://dx.doi.org/10.1016/j.jenvman.2024.121326 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Center for Genomic Integrity, Institute for Basic Science, Ulsan 44919, Republic of Korea.
Combination therapies using checkpoint inhibitors with immunostimulatory agonists have attracted great attention due to their synergistic therapeutic effects for cancer treatment. However, such combination immunotherapies require specific timing of doses to show sufficient antitumor efficacy. Sequential treatment usually requires multiple administrations of the individual drugs at specific time points, thus increasing the complexity of the drug regimen and compromising patient compliance.
View Article and Find Full Text PDFPLoS One
January 2025
Department of Crop and Soil Sciences, College of Agricultural and Environmental Sciences, University of Georgia, Griffin, Georgia, United States of America.
Previous studies have indicated the great performance of electrooxidation (EO) to mineralize per- and polyfluoroalkyl substances (PFASs) in water, but different anions presented in wastewater may affect the implementation of EO treatment in field applications. This study invetigated EO treatment of perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA), two representative perfluoroalkyl acids (PFAAs), using porous Magnéli phase titanium suboxide anodes in electrolyte solutions with different anions present, including NO3-, SO42-, CO32- and PO43-. The experiment results indicate that CO32- enhanced PFAS degradation, while NO3- suppressed the degradation reactions with its concentration higher than 10 mM.
View Article and Find Full Text PDFMikrochim Acta
January 2025
Public Health School, Mudanjiang Medical University, Mudanjiang, China.
Natural enzymes are a class of biological catalysts that can catalyze a specific substrate. Although natural enzymes have catalytic activity, they are susceptible to the influence of external environment such as temperature, and storage requirements are more stringent. Since the first discovery of magnetic FeO nanoparticles with peroxidase-like activity in 2007, the research on nanoenzymes has entered a rapid development stage.
View Article and Find Full Text PDFACS Appl Polym Mater
July 2024
Departament d'Enginyeria Química, Campus Diagonal Besòs (EEBE), Universitat Politècnica de Catalunya Barcelona Tech, Av. Eduard Maristany 10-14, Barcelona 08019, Spain.
Diabetes is a metabolic disorder caused by the body's inability to produce or use insulin. Considering the figures projected by the World Health Organization, research on insulin therapy is crucial. Hence, we present a soft biointerface based on a thiol-yne poly(ethylene glycol) (PEG) click-hydrogel as an advanced treatment option to administrate insulin.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
School of Mechanical Science and Engineering, Northeast Petroleum University, 199 Fazhan Road, Daqing 163318, P. R. China.
The actual ORR catalytic activity of perovskite materials is significantly lower than the theoretical value due to their inherently low specific surface area and significant segregation of inactive oxygen ions on the surface. This study reports a sol-gel synthesis approach that employs glucose as a structural regulator to fabricate LaSrMnO (LSM) perovskites. Compared with the original LSM (12.
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