One of the primary contributors to automobile exhaust pollution is the significant deviation between the actual and theoretical air-fuel ratios during transient conditions, leading to a decrease in the conversion efficiency of three-way catalytic converters. Therefore, it becomes imperative to enhance fuel economy, reduce pollutant emissions, and improve the accuracy of transient control over air-fuel ratio (AFR) in order to mitigate automobile exhaust pollution. In this study, we propose a Linear Active Disturbance Rejection Control (LADRC) Hydrogen Doping Compensation Controller (HDC) to achieve precise control over the acceleration transient AFR of gasoline engines. By analyzing the dynamic effects of oil film and its impact on AFR, we establish a dynamic effect model for oil film and utilize hydrogen's exceptional auxiliary combustion characteristics as compensation for fuel loss. Comparative experimental results demonstrate that our proposed algorithm can rapidly regulate the AFR close to its ideal value under three different transient conditions while exhibiting superior anti-interference capability and effectively enhancing fuel economy.
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http://dx.doi.org/10.1016/j.heliyon.2024.e30865 | DOI Listing |
Langmuir
January 2025
Department of Chemistry, Bharathiar University, Coimbatore 641 046, India.
Developing nonprecious metal-based electrocatalysts with exceptional activity and durability for water electrolysis remains a significant challenge. Herein, we report a highly efficient bifunctional electrocatalyst composed of sulfur-doped vanadium metal-organic frameworks (S@V-MOF) integrated with multiwalled carbon nanotubes (MWCNTs) to promote the synergistic effect between S@V-MOF and MWCNTs and modulate the electronic structure of the catalyst, which eventually enhanced its electrocatalytic performance. The S@V-MOF/MWCNT catalyst loaded at the Ni foam electrode exhibits remarkable activity for both the hydrogen evolution reaction (HER) in acidic media and oxygen evolution reaction (OER) in alkaline media, requiring overpotentials of 48 and 227 mV, respectively, to reach a current density of 10 mA cm.
View Article and Find Full Text PDFACS Nano
January 2025
Songshan Lake Materials Laboratory (SLAB), Dongguan 523808, P. R. China.
Electrocatalytic CO reduction into high-value multicarbon products offers a sustainable approach to closing the anthropogenic carbon cycle and contributing to carbon neutrality, particularly when renewable electricity is used to power the reaction. However, the lack of efficient and durable electrocatalysts with high selectivity for multicarbons severely hinders the practical application of this promising technology. Herein, a nanoporous defective AuCu single-atom alloy (De-AuCu SAA) catalyst is developed through facile low-temperature thermal reduction in hydrogen and a subsequent dealloying process, which shows high selectivity toward ethylene (CH), with a Faradaic efficiency of 52% at the current density of 252 mA cm under a potential of -1.
View Article and Find Full Text PDFChemistry
January 2025
University of Leipzig, Physics and Geoscience, Linnestr. 5, 4103, Leipzig, GERMANY.
The development of smart materials capable of separating dihydrogen isotopologues has risen recently. Among potential candidates, the flexible MIL-53 (Al) has been gaining attention due to its structural flexibility providing the so-called ''breathing mechanism'' that can be useful to separate hydrogen isotopologues selectively. In the present work, an in situ continuous wave electron paramagnetic resonance investigation has been proven as a sensitive technique to follow the isotopologue-selective adsorption-desorption of dihydrogen species on the paramagnetic metal-doped MIL-53 (Al0.
View Article and Find Full Text PDFInorg Chem
January 2025
College of Physical Science and Technology, Yangzhou University, Yangzhou 225002, People's Republic of China.
Replacing the sluggish anodic water oxidation reaction with the glucose oxidation reaction (GOR) offers an energy-saving strategy to obtain value-added products during the hydrogen production process. However, rational design of the GOR electrocatalyst with an explicit structure-property relationship remains a challenge. In this study, by using cobalt chalcogenides as model catalysts, we performed an in-depth study of the GOR catalytic mechanism of CoS and CoSe nanosheets.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
Guangdong Key Laboratory of Materials and Equipment in Harsh Marine Environment, School of Ocean Engineering, Guangzhou Maritime University, Guangzhou 510725, China.
Metal oxide semiconductor (MOS) hydrogen sensors offer advantages, such as high sensitivity and fast response, but their challenges remain in achieving low-cost fabrication and stable operation at room temperature. This study investigates Nb-doped TiO (NTO) thin films prepared via a one-step micro-arc oxidation (MAO) with the addition of NbO nanoparticles into the electrolyte for room-temperature hydrogen sensing. The characterization results revealed that the incorporation of NbO altered the film's morphology and phase composition, increasing the Nb content and forming a homogeneous composite thin film.
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