Moisture-resistant radical anions of quinoxalin-2(1)-ones in aerial dioxygen activation.

Org Biomol Chem

School of Chemical Sciences, National Institute of Science Education and Research (NISER) Bhubaneswar, An OCC of Homi Bhabha National Institute, PO Bhimpur-Padanpur, Via Jatni, District Khurda, Odisha 752050, India.

Published: June 2024

This study demonstrates the successful formation of a radical anion intermediate in a moist atmosphere, facilitating chemical reactions by activating aerial dioxygen through a single electron transfer (SET) mechanism. Derived from deprotonating quinoxaline-2(1)-one with KOBu, it shows potential in oxygenation chemistry. Validation comes from radical scavenging and EPR experiments.

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Source
http://dx.doi.org/10.1039/d4ob00673aDOI Listing

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