Water is the source of life and civilization, but water icing causes catastrophic damage to human life and diverse industrial processes. Currently, superhydrophobic surfaces (inspired by the lotus effect) aided anti-icing attracts intensive attention due to their energy-free property. Here, recent advances in anti-icing by design and functionalization of superhydrophobic surfaces are reviewed. The mechanisms and advantages of conventional, macrostructured, and photothermal superhydrophobic surfaces are introduced in turn. Conventional superhydrophobic surfaces, as well as macrostructured ones, easily lose the icephobic property under extreme conditions, while photothermal superhydrophobic surfaces strongly rely on solar illumination. To address the above issues, a potentially smart strategy is found by developing macrostructured photothermal storage superhydrophobic (MPSS) surfaces, which integrate the functions of macrostructured superhydrophobic materials, photothermal materials, and phase change materials (PCMs), and are expected to achieve all-day anti-icing in various fields. Finally, the latest achievements in developing MPSS surfaces, showcasing their immense potential, are highlighted. Besides, the perspectives on the future development of MPSS surfaces are provided and the problems that need to be solved in their practical applications are proposed.
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http://dx.doi.org/10.1002/adma.202402897 | DOI Listing |
ACS Appl Mater Interfaces
December 2024
College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, China.
Polyurethane sponge is frequently selected as a substrate material for constructing flexible compressible sensors due to its excellent resilience and compressibility. However, being highly hydrophilic and flammable, it not only narrows the range of use of the sensor but also poses a great potential threat to human safety. In this paper, a conductive flexible piezoresistive sensor (CHAP-PU) with superhydrophobicity and high flame retardancy was prepared by a simple dip-coating method using A-CNTs/HGM/ADP coatings deposited on the surface of a sponge skeleton and modified with polydimethylsiloxane.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
School of Biological Engineering, Xinxiang Institute of Engineering, Xinxiang 453700, China.
A self-healing superhydrophobic coating was successfully prepared in the present work. The coating comprised PEG (polyethylene glycol) and FeO nanoparticles modified with stearic acid (SA) via hydrogen bonds, using polyamide resin and epoxy as binders. The chemically damaged surface could restore its original superhydrophobic structure and chemical composition after 4 h at room temperature or 10 min of heating in an oven with a self-healing efficiency of 95.
View Article and Find Full Text PDFBiomimetics (Basel)
December 2024
Department of Chemistry, Institute of Nanotechnology and Advanced Materials, Bar-Ilan University, Ramat-Gan 5290002, Israel.
Developing a durable multifunctional superhydrophobic coating on polymeric films that can be industrially scalable is a challenge in the field of surface engineering. This article presents a novel method for a scalable technology using a simple single-step fabrication of a superhydrophobic coating on polymeric films that exhibits excellent water-repelling and UV-blocking properties, along with impressive wear resistance and chemical robustness. A mixture of titanium precursors, tetraethylorthosilicate (TEOS), hydrophobic silanes and silica nano/micro-particles is polymerized directly on a corona-treated polymeric film which reacts with the surface via siloxane chemistry.
View Article and Find Full Text PDFLangmuir
December 2024
School of Computer and Artifitial Intelligence, Beijing Technology and Business University, Beijing 100048, China.
Inspired by the ultrafast directional water transport structure of Sarracenia trichomes, hierarchical textured surfaces with specific microgrooves were prepared based on laser processing combined with dip modification, in response to the growing problem of freshwater scarcity. The prepared surfaces were tested for droplet transport behavior to investigate the relationship between the surface structure and the driving force of directional water transport and their effects on the water transport distance and water transport velocity. The results showed that surfaces with a superhydrophobic background associated channels of multirib structures, and a dual-gradient surface of gradient hydrophobic background associated channels with gradient structure performed the best in terms of water transport efficiency.
View Article and Find Full Text PDFAdv Mater
December 2024
Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, Shaanxi Key Laboratory for Advanced Energy Devices, Shaanxi Engineering Lab for Advanced Energy Technology School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119, P. R. China.
The rapidly increased efficiency of perovskite solar cells (PSCs) indicates their broad commercial prospects, but the commercialization of perovskite faces complex optimization processes and stability issues. In this work, a simple optimized strategy is developed by the addition of trimethylgermanium chloride (TGC) into FACsPbI precursor solution. TGC triggers the successive interactions in perovskite solution and film, involving the hydrolysis of vulnerable Ge─Cl bond forming Ge─OH group, then forming the hydrogen bonds (O─H···N and O─H···I) with FAI.
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