Synthesis, Photophysical, and Optical Limiting Properties of Twistacene-Functionalized Arenes.

To realize the relationship of structure and property, four novel twistacene-functionalized arenes, namely, 1,4-bis(2,7-di--butyl-9,14-bis(4-(-butyl)phenyl)dibenzo[,]tetracen-11-yl)buta-1,3-diyne (), 1,4-bis(3,5,10,12-tetra--butyltribenzo[,,]coronen-16-yl)buta-1,3-diyne (), 1,4-bis(2,7-di--butyl-9,14-bis(4-(-butyl)phenyl)dibenzo[,]tetracen-10-yl)buta-1,3-diyne (), 1,4-bis(3,5,10,12-tetra--butyltribenzo[,,]coronen-15-yl)buta-1,3-diyne (), linked with butadiyne as π bridges have been strategically synthesized and characterized. The nonlinear optical properties are detailly examined in solution through the open-aperture Z-scan method in a comparative manner, indicating that molecules and exhibit better nonlinear optical responses than and . Among them, and exhibit excellent optical limiting responses with limiting thresholds of 0.17 and 0.19 J/cm, respectively, being superior to the state-of-the-art material C. The ultrafast transient absorption test and DFT calculations suggest that the nonlinear absorption mechanisms belong to TPA-induced ESA. In addition, the effective percentage calculated from TD-DFT can provide a brief glance to evaluate the optical limiting performance.