Occurrence, dissipation and processing factors of multi-pesticides in goji berry.

As medicine and food homology substance, goji berry is consumed worldwide in the form of fresh, dried and juice; however, pesticide residues have become one of the problems that essentially threaten its quality during cultivation and processing. In this study, a total of 75 dried goji berries were sampled from markets across China, and for the determination of 62 analytes, 28 pesticides were identified. Nine pesticides with high detectable rates and residual levels were selected for folia spraying, and their half-lives were found to range from 1.04 to 2.21 d. The processing factors (PFs) of juice were between 0.25 and 1.02, and this was mainly related with their octanol-water partition coefficient (logKow values). Washing could reduce pesticides residues to varying degrees with the removal rates between 17.00% and 74.05%. Sun drying with higher PF values in the range of 0.61-5.91 exhibited more obvious enrichment effect compared to oven drying. Commercial goji berry had cumulative chronic dietary risks with the hazard index (HI) values of 1.61%-4.97%. Its acute risk quotients (HQs) for consumers were 543.32%-585.92% and were mainly due to insecticides. These results provide important references for rationalizing pesticide application during goji berry cultivation and for the improvement of process to ensure food safety.