Crystalline nanosheets of three-dimensional supramolecular frameworks with uniform thickness and high stability.

Fabricating three dimensional (3D) supramolecular frameworks (SMFs) into stable crystalline nanosheets remains a great challenge due to the homogeneous and weak inter-building block interactions along 3D directions. Herein, crystalline nanosheets of a 3D SMF with a uniform thickness of 4.8 ± 0.1 nm immobilized with Pt nanocrystals on the surface (Q[8]/Pt NSs) were fabricated the solid-liquid reaction between cucurbit[8]uril/HPtCl single crystals and hydrazine hydrate with the help of gas and heat yielded during the reaction process. A series of experiments and theoretical calculations reveal the ultrahigh stability of Q[8]/Pt NSs due to the high density hydrogen bonding interaction among neighboring Q[8] molecules. This in turn endows Q[8]/Pt NSs with excellent photocatalytic and continuous thermocatalytic CO oxidation performance, representing the thus-far reported best Pt nano-material-based catalysts.