AI Article Synopsis
- Electrochemical methods are gaining popularity in green chemistry due to their potential for sustainability.
- Understanding reactions at the electrode-solution interface is key, and the study uses a combination of techniques, including voltammetry and mass spectrometry, for real-time monitoring.
- The research reveals important insights into the electrocatalytic processes involved in the reduction of oxygen, showing reaction intermediates and degradation pathways, which could improve optimization in sustainable electrochemical reactions.
Article Abstract
Electrochemical steps are increasingly attractive for green chemistry. Understanding reactions at the electrode-solution interface, governed by kinetics and mass transport, is crucial. Traditional insights into these mechanisms are limited, but our study bridges this gap through an integrated approach combining voltammetry, electrochemical impedance spectroscopy, and electrospray ionization mass spectrometry. This technique offers real-time monitoring of the chemical processes at the electrode-solution interface, tracking changes in intermediates and products during reactions. Applied to the electrochemical reduction of oxygen catalyzed by the iron(II) tetraphenyl porphyrin complex, it successfully reveals various reaction intermediates and degradation pathways under different kinetic regimes. Our findings illuminate complex electrocatalytic processes and propose new ways for studying reactions in alternating current and voltage-pulse electrosynthesis. This advancement enhances our capacity to optimize electrochemical reactions for more sustainable chemical processes.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11157527 | PMC |
| http://dx.doi.org/10.1021/jacs.4c04989 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Highly Elastic Spongelike Hydrogels for Impedance-Based Multimodal Sensing.
ACS Nano
January 2025
School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Republic of Singapore.
Hydrogel-based sensors have been widely studied for perceiving the environment. However, the simplest type of resistive sensors still lacks sensitivity to localized strain and other extractable data. Enhancing their sensitivity and expanding their functionality to perceive multiple stimuli simultaneously are highly beneficial yet require optimal material design and proper testing methods.
View Article and Find Full Text PDFEnhancing muscle and brain resilience: The role of prehabilitative exercise in mitigating disuse effects.
J Physiol
January 2025
Institute of Sports Medicine Copenhagen, Department of Orthopaedic Surgery, Copenhagen University Hospital - Bispebjerg and Frederiksberg, Copenhagen, Denmark.
Short-term disuse leads to rapid declines in muscle mass and strength. These declines are driven by changes at all levels of the neuromuscular system; the brain, spinal cord and skeletal muscle. In addition to neural input from the central and peripheral nervous systems to the muscle, molecular factors originating in the muscle can be transported to the central nervous system.
View Article and Find Full Text PDFChlorine-Doped SnO2 Nanoflowers on Nickel Hollow Fiber for Enhanced CO2 Electroreduction at Ampere-level Current Densities.
Angew Chem Int Ed Engl
January 2025
Shanghai Advanced Research Institute Chinese Academy of Sciences: Chinese Academy of Sciences Shanghai Advanced Research Institute, Low-Carbon Conversion Science and Engineering Cente, 100 Haike Road, 201203, Shanghai, CHINA.
Renewable energy-driven electrochemical CO2 reduction has emerged as a promising technology for a sustainable future. However, achieving efficient production of storable liquid fuels at ampere-level current densities remains a significant hurdle in the large-scale implementation of CO2 electroreduction. Here we report a novel catalytic electrode comprising chlorine-doped SnO2 nanoflowers arrayed on the exterior of three-dimensional nickel hollow fibers.
View Article and Find Full Text PDFReduced expression of the serotonin transporter impacts mitochondria in a sexually dimorphic manner.
Biochem Biophys Rep
March 2025
School of Biological Sciences, Victoria University of Wellington Kelburn, Parade, 6012, Wellington, New Zealand.
Neuropsychiatric and neurodevelopmental disorders are complex conditions that arise from a variety of interacting genetic and environmental factors. Among these factors, altered serotonergic signalling and mitochondrial dysfunction are strongly implicated, with a growing body of evidence to suggesting that serotonergic signalling is an important regulator of mitochondrial biogenesis. The serotonin transporter (SERT) functions to regulate synaptic 5-HT, and human allelic variants of the serotonin reuptake transporter-linked polymorphic region (5-HTTLPR) are associated with reduced SERT expression and increased susceptibility for developing neuropsychiatric disorders.
View Article and Find Full Text PDFLipid imbalance and inflammatory oxylipin cascade at the maternal-fetal interface in recurrent spontaneous abortion.
Heliyon
December 2024
Department of Obstetrics and Gynaecology, The Second Affiliated Hospital of Chongqing Medical University, Chongqing, China.
Background: Recurrent spontaneous abortion (RSA) is intricately linked to metabolic dysregulation at the maternal-fetal interface during early gestation. Abnormal levels of essential fatty acids and downstream oxylipins in decidua and chorionic villi have been identified as potential risk factors for RSA. Oxylipins have been linked to excessive inflammation, which might disrupt maternal-fetal immune tolerance, potentially contributing to RSA.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!