Electronic redistribution through the interface of MnCoO-NiN nano-urchins prompts rapid phase transformation for enhanced oxygen evolution reaction.

One of the most coveted objectives in the realm of energy conversion technologies is the development of highly efficient and economically viable electrocatalysts for the oxygen evolution reaction. The commercialization of such techniques has thus far been impeded by their slow response kinetics. One of the many ways to develop highly effective electrocatalysts is to judiciously choose a coupling interface that maximizes catalyst performance. In this study, the electrochemical phase transformation of MnCoO-NiN into MnCoO-NiOOH is described. The catalyst has an exceptional overpotential of 224 mV to drive a current density of 10 mA cm. Strong interfacial contact is seen in the MnCoO-NiN catalyst, leading to a considerable electronic redistribution between the MnCoO and NiN phases. This causes an increase in the valence state of Ni, which makes it an active site for the adsorption of *OH, O*, and *OOH (intermediates). This charge transfer facilitates the rapid phase transformation to form NiOOH from NiN. At a higher current density of 300 mA cm, the catalyst remained stable for a period of 140 h. DFT studies also revealed that the -formed NiOOH on the MnCoO surface results in superior OER kinetics compared to that of NiOOH alone.