Using the existing architecture of [Dy(Tp)F] that supports a terminal Dy-F bond, the synthesis and isolation of [Dy(Tp)F(THF)](PF) and its diamagnetic yttrium analogue have been achieved. Alternating current magnetic susceptibility studies show an increased effective energy barrier of = 661(6) cm (951(8) K), the highest yet reported for a high coordinate ( > 8) lanthanide single-ion magnet.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d4dt01194e | DOI Listing |
Publication Analysis
Top Keywords
energy barrier
8
high coordinate
8
coordinate lanthanide
8
lanthanide single-ion
8
approaching 1000
4
1000 energy
4
barrier high
4
single-ion magnets
4
magnets increasing
4
increasing [dytpf]
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!