The defects have a remarkable influence on the electronic structures and the electric transport behaviors of the matter, providing the additional means to engineering their physical properties. In this work, a comprehensive study on the effect of Br-vacancies on the electronic structures and transport behaviors in the high-order topological insulator BiBr is performed by the combined techniques of the scanning tunneling microscopy (STM), angle-resolved photoemission spectroscopy (ARPES), and physical properties measurement system along with the first-principle calculations. The STM results show the defects on the cleaved surface of a single crystal and reveal that the defects are correlated to the Br-vacancies with the support of the simulated STM images. The role of the Br-vacancies in the modulation of the band structures has been identified by ARPES spectra and the calculated energy-momentum dispersion. The relationship between the Br-vacancies and the semiconducting-like transport behaviors at low temperature has been established, implying a Mott variable ranging hopping conduction in BiBr. The work not only resolves the unclear transport behaviors in this matter, but also paves a way to modulate the electric conduction path by the defects engineering.

Download full-text PDF

Source
http://dx.doi.org/10.1002/smtd.202400517DOI Listing

Publication Analysis

Top Keywords

transport behaviors
16
variable ranging
8
ranging hopping
8
hopping conduction
8
high-order topological
8
topological insulator
8
insulator bibr
8
electronic structures
8
behaviors matter
8
physical properties
8

Similar Publications

Electric transportation and electroreception in hummingbird flower mites.

Proc Natl Acad Sci U S A

February 2025

School of Biological Sciences, Life Sciences Department, University of Bristol, Bristol BS8 1TQ, England.

Electric fields in terrestrial environments are used by caterpillars to detect their predators, as foraging cues by pollinators, and facilitate ballooning by spiders. This study shows that electric fields facilitate transportation and detection of hummingbirds in a guild of tropical phoretic mites. Hummingbird flower mites feed on nectar and pollen and complete their life cycle inside flowers.

View Article and Find Full Text PDF

As urbanization intensifies and the need for sustainable transportation grows, Mobility as a Service (MaaS) emerges as a promising solution to urban mobility challenges. This study seeks to explore the underlying mechanisms of MaaS from a sustainability perspective and to assess its impact on service experience and user satisfaction. Additionally, it examines how user satisfaction influences the broader adoption of MaaS.

View Article and Find Full Text PDF

Geospatial and econometric approaches or older driver safety: Analysis of crash injury severity of regional highways.

PLoS One

January 2025

State Key Laboratory of Automotive Safety and Energy, School of Vehicle and Mobility, Tsinghua University, Beijing, China.

This study tried to focus on the older drivers' group and explore the impact factors of injury severity involving older drivers from geo-spatial analysis. To reach the goal, a spatial analysis was proposed employing geographic information systems (GIS) with a case study application to two counties in Nevada. First, crash clusters were explored using Density-Based Spatial Clustering of Applications with Noise (DBSCAN) approach to investigate the spatial crash pattern for older drivers, and determine high risk locations of injury severity.

View Article and Find Full Text PDF

We employed machine learning (ML) techniques combined with potential-dependent photoelectrochemical impedance spectroscopy (pot-PEIS) to gain deeper insights into the charge transport mechanisms of hematite (α-FeO) photoanodes. By the Shapley Additive exPlanations (SHAP) analysis from the ML model constructed from a small data set (dozens of samples) of electrical parameters obtained from pot-PEIS and the PEC performance, we identified the dominant factors influencing the electron transport to the back contact in the bulk and hole transfer to a solution at the hematite/electrolyte interface. The results revealed that shallow defect states significantly enhance electron transport, while deep defect states impede it, and also one of the surface states enhances the hole transfer to the electrolyte solution.

View Article and Find Full Text PDF

Nowadays, intracerebral hemorrhage (ICH) is the main cause of death and disability, and motor impairment is a common sequel to ICH. Electroacupuncture (EA) has been widely used for functional recovery after ICH. However, its role and associated regulatory mechanisms in rehabilitation after ICH remain poorly understood.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!