Unveiling the power of MXenes: Solid lubrication perspectives and future directions.

The interaction between two surfaces leads to the generation of friction and wear of material. Friction and wear are some of the major challenges that may readily be overcome by the third part of tribology called lubrication. Utilizing solid lubricants including polymers, carbon-based materials, soft metals, transition metal dichalcogenides, along with their potential benefits and drawbacks in dry environments can reduce friction. Recently, an emerging class of two-dimensional (2D) transition metal nitrides, carbides or carbonitrides commonly known as MXenes have emerged as an attractive alternative for solid lubrication because of their ability to establish wear-resistant tribo layers and well as low friction and shear strength. Furthermore, the inherent hydrophilic nature of these substances has led to limited dispersion stability and phase compatibility when combined with pure base oils. As a result, their potential use as solid lubricants and lubricant additives has been impeded. To address this issue and enhance the applicability of MXenes as solid lubricants, their surface modification can be an attractive tool. Therefore, this review provides a succinct summary of the current state-of-the-art in surface functionalization of MXenes, a subject that has not yet been thoroughly addressed. Further, the mechanical behavior of MXenes and composites has been discussed, followed by the potential of MXenes as a solid lubricant at micro- and macro-scale. Finally, the existing opportunities and challenges of the research area have been discussed with possible future research directions. We believe, this article will be a valuable resource for MXenes and opens the door to improve the chemical, physical and mechanical properties of MXenes in various applications, such as solid lubrication.