We calculate the spectral properties of two related families of non-Hermitian free-particle quantum chains with N-multispin interactions (N=2,3,...). The first family have a Z(N) symmetry and are described by free parafermions. The second have a U(1) symmetry and are generalizations of XX quantum chains described by free fermions. The eigenspectra of both free-particle families are formed by the combination of the same pseudo-energies. The models have a multicritical point with dynamical critical exponent z=1. The finite-size behavior of their eigenspectra, as well as the entanglement properties of their ground-state wave function, indicate the models are conformally invariant. The models with open and periodic boundary conditions show quite distinct physics due to their non-Hermiticity. The models defined with open boundaries have a single conformal invariant phase, while the XX multispin models show multiple phases with distinct conformal central charges in the periodic case.
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http://dx.doi.org/10.1103/PhysRevE.109.044138 | DOI Listing |
RSC Adv
January 2025
Graduate School of Human Development and Environment, Kobe University 3-11, Tsurukabuto, Nada-ku Kobe Hyogo 657-0011 Japan
Polyamide 6 (PA6) in its α and γ-forms was studied from 30 to 220 °C using Raman spectroscopy in the low- and high-wavenumber regions. Quantum chemical calculations were employed to assist with band assignments. In the low-wavenumber region, a peak at approximately 100 cm, attributable to a mixed mode of methylene lateral motion and amide group stretching, was observed.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Key Laboratory of Biocatalysis and Enzyme Engineering, Hubei University, Wuhan 430062, China. Electronic address:
n-Alkyltrimethylammonium bromide (CTAB)-based deep eutectic solvent (DESs) has potential in the efficient delignification and utilization of carbohydrates in biomass. In this research, DESs containing Brønsted acid and Lewis acid were prepared with CTAB (alkyl-chain length 12-18), organic acids and metal chlorides, and the optimal treatment conditions were acquired by pretreatment optimization. Through the pretreatment with TTAB/LCA/Fe (1:4:0.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, Shanghai Frontiers Science Center of Molecule Intelligent Syntheses, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China.
Chemical kinetics for second oxygen addition reactions (·QOOH + O) of long-chain alkanes are of great importance in low-temperature combustion technologies. However, kinetic data for key reactions of ·QOOH + O systems are often difficult to obtain experimentally and are primarily estimated or calculated by using theoretical methods. In this work, barrier heights (BHs), reaction energies (Δs), and relative energies (REs) of stationary points for key reactions of two representative ·QOOH + O systems in the low-temperature oxidation of -butyl as well as pressure-dependent rate constants for the involved reactions are calculated with the high-level quantum chemical method CCSD(T)-F12b/CBS.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Chemical and Biological Engineering, Sookmyung Women's University, Seoul 04310, Korea.
Advancements in printing techniques are essential for fabricating next-generation displays. Lead halide perovskites demonstrate great potential as light emitters of solution-processed light-emitting diodes (LEDs). In particular, the perovskite/polymer composite emitters exhibit exceptional luminescent characteristics, mechanical flexibility, and environmental stability due to the improved film morphologies and defect passivation achieved through the introduction of polymer additives.
View Article and Find Full Text PDFInt J Legal Med
January 2025
Biological and Life Sciences, School of Arts and Sciences, Ahmedabad University, Central Campus, Navrangpura, Ahmedabad, Gujarat, India.
Polymerase Chain Reaction (PCR) has transformed forensic DNA analysis but is still limited when dealing with compromised trace or inhibitor-containing samples. Nanotechnology has been integrated into nanoPCR (nanoparticle-assisted PCR) to overcome these obstacles. Nanomaterials improve PCR sensitivity, selectivity, and efficiency.
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