Electroreductive ring-opening carboxylation of styrene carbonates with CO to achieve dicarboxylic acids and/or -hydroxy acids has been developed the selective cleavage of the C(sp)-O bond in cyclic carbonates. The product selectivity is probably determined by the stability and reactivity of the key benzylic radical and carbanion intermediate.
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| http://dx.doi.org/10.1039/d4cc01695e | DOI Listing |
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