Reactions that change the identity of an atom within a ring system are emerging as valuable tools for the site-selective editing of molecular structures. Herein, we describe the expansion of an underdeveloped transformation that directly converts azaarene-derived -oxides to all-carbon arenes. This ring transmutation exhibits good functional group tolerance and replaces the -oxide moiety with either unsubstituted, substituted, or isotopically labeled carbon atoms in a single laboratory operation.
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| http://dx.doi.org/10.1021/acs.orglett.4c01263 | DOI Listing |
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