-selective C-H borylation of aromatic ketones has not been extensively explored. Herein, we report the iridium-catalyzed -selective C-H borylation of aromatic ketones using in situ-formed imine as the ligand. Good compatibility is observed for various substituted acetophenones and other aromatic ketones, and corresponding products are obtained with medium to excellent yields.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/acs.orglett.4c01067 | DOI Listing |
Publication Analysis
Top Keywords
-selective c-h
12
c-h borylation
12
aromatic ketones
12
iridium-catalyzed -selective
8
borylation aromatic
8
borylation aryl
4
ketones
4
aryl ketones
4
ketones transient
4
transient imine
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!