The title compound, [Ag(CHNS)]ClO·2CHOH, is monoclinic. The Ag atom is coordinated by pyrido N atoms and is two-coordinate; however, the Ag atom has nearby O atoms that can be assumed to be weakly bonded - one from the perchlorate anion and one from the methanol solvate molecule. One of the thienyl groups on a 2,3-bis-(thio-phen-2-yl)pyrido[3,4-]pyrazine is flipped disordered and was refined to occupancies of 68.4 (6) and 31.6 (6)%.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11074545 | PMC |
| http://dx.doi.org/10.1107/S2414314624003444 | DOI Listing |
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