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Atmospheric water harvesting (AWH) technology has attracted significant attention as an effective strategy to tackle the global shortage of freshwater resources. Work has focused on the use of hydrogel-based composite adsorbents in water harvesting and water conservation. The approaches adopted to make use of hygroscopic inorganic salts which subject to a "salting out" effect. In this study, we report the first use of modified UIO-66-NH as a functional steric cross-linker and Sa-son seed gum was used as polymeric substrate to construct super hygroscopic hydrogels by free radical copolymerization. The maximum water uptake on SMAGs (572 cm·g) outperforms pure UIO-66-NH (317 cm·g). Simultaneously, our first attempt to use it for anti-evaporation applications in an arid environment (Lanzhou, China) simulating sandy areas. The evaporation rate of the anti-evaporation material treated with 0.20 % super moisture-absorbent gels (SMAGs) decreased by 6.1 % over 64 h period under natural condition in Lanzhou, China. The prepared material can not only absorb liquid water but also water vapor, which can provide a new way for water collection and conservation technology. The design strategy of this material has wide applications ranging from atmospheric water harvesting materials to anti-evaporation technology.
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http://dx.doi.org/10.1016/j.ijbiomac.2024.132158 | DOI Listing |
Chem Sci
December 2024
Department of Chemistry, University of Warwick Coventry CV4 7AL UK
Self-assembling cyclic peptide nanotubes are fascinating supramolecular systems with promising potential for various applications, such as drug delivery, transmembrane ionic channels, and artificial light-harvesting systems. In this study, we present novel pH-responsive nanotubes based on asymmetric cyclic peptide-polymer conjugates. The pH response is introduced by a tertiary amine-based polymer, poly(dimethylamino ethyl methacrylate) (pDMAEMA) or poly(diethylamino ethyl methacrylate) (pDEAEMA) which is protonated at low pH.
View Article and Find Full Text PDFHeliyon
December 2024
The Key Laboratory of Agro-Environment in Midstream of Yangtze Plain, Ministry of Agriculture, The Key Laboratory of Prevention, Control and Remediation of Soil Heavy Metal Pollution in Hunan Province, Institute of Agro-Environment and Ecology, Hunan Academy of Agricultural Sciences, Changsha, 410125, PR China.
Cadmium (Cd) and arsenic (As) contamination risk in paddy soils has raised global concern. In order to scientifically and objectively evaluate the bioavailability of soil Cd, As and the risk of Cd or As threshold in contaminated farmland, this study was conducted to investigate different types of extractants for their potential extraction efficiency of Cd and As. Soils from two different parent materials in Hunan, Yueyang and Yiyang, typical double-cropping rice production areas in the south of China, were used as test soils.
View Article and Find Full Text PDFPLoS One
December 2024
Department of Botany, Bahauddin Zakriya University, Multan, Pakistan.
Drought-induced stress presents a substantial threat as it disrupts the normal growth of cereal crops and leads to decreased yields. The persistent occurrence of drought conditions significantly impacts the growth and development of pearl millet. This study aimed to explore how calcium chloride (CaCl2) regulates the growth of pearl millet when it faces a lack of water.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Chinese Academy of Sciences, Institute of Chemistry, 2 Bei Yi Jie, Zhong Guan Cun, 100190, Beijing, CHINA.
Molecular frameworks have recently shown a great potential in atmospheric water harvesting, in which the water release at low temperatures is challenging. Anion-organic frameworks based on anion-coordination chemistry are presented herein to meet this challenge. These frameworks are prepared as tubular single crystals in pure water from the in-situ protonation and crystallization of pyridine-terminated triphenylamine derivatives with hydrochloric or hydrobromic acid.
View Article and Find Full Text PDFSci Total Environ
December 2024
Leibniz University Hannover, Ludwig Franzius Institute of Hydraulic, Estuarine and Coastal Engineering, Nienburger Str. 4, Hannover 30167, Germany.
Seagrass meadows are one of the most productive ecosystems of the world. Seagrass enhances biodiversity, sequesters CO and functions as a coastal protection measure by mitigating waves and enhancing sedimentation. However, populations are declining in many regions and natural recolonization of bare sediment beds is protracted and unlikely.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!