Biochar is an eco-friendly carbon material whose properties allow it to be used as a sorbent for wastewater treatment or soil remediation. The paper presents the results of research related to the pyrolysis process of apple waste after supercritical CO extraction with the simultaneous use of physical activation. The research assessed the influence of the temperature of the pyrolysis process and steam activation on the structural properties of the obtained biochar, i.e. specific surface, porous structure, and presence of functional groups. The results obtained confirmed that lower temperature pyrolysis produces biochar characterised by the presence of functional groups and ordered structure. On the other hand, high temperature pyrolysis with simultaneous steam activation determines microporosity and high values of the specific surface area. Taking into consideration pollutant sorption mechanisms (physical and chemical sorption), the obtained biochar materials can be used as sorbents in water and wastewater treatment.
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http://dx.doi.org/10.1038/s41598-024-61394-8 | DOI Listing |
Heliyon
January 2025
Laser and Plasma Research Institute, Shahid Beheshti, University, G.C., Evin, 19839-63113, Tehran, Iran.
One of the best and most advanced methods for disposal of urban, hospital, industrial, and other hazardous waste is to convert waste into combustible gases in reactors based on plasma arc technology. Also used for renewable energy generation, this technology involves thermal treatment without a combustion process; therefore, the waste is completely decomposed into simple molecules in a near vacuum environment almost devoid of Oxygen at elevated temperatures. The present research uses a thermal transferred arc plasma reactor to conduct a feasibility study on the pyrolysis of three types of wastes: Antar, Orthotoluenediamine (OTD), and Tar.
View Article and Find Full Text PDFSci Rep
January 2025
College of Civil Engineering, Liaoning Technical University, Fuxin, 123000, China.
The adsorption of phosphate in the collected water is crucial to alleviate the crisis of phosphorus resources, which is in line with the concept of green and sustainable development of resources. In this study, based on the calcium modification technology of pyrolysis combined with chemical modification, a new type of calcium modified coal gangue (CaMCG) was prepared by using coal gangue as raw material and calcium chloride as modifier for the removal of phosphate.The optimum preparation conditions of CaMCG were obtained by response surface test: m:m=1, calcination temperature 735℃, calcination time 135 min.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Research Institute of Wood Industry, Chinese Academy of Forestry, Haidian, Beijing 100091, China. Electronic address:
In order to increase the added value of Xanthoceras Sorbifolia Bunge (XSB) and to obtain green biomass activated carbon with abundant pores for efficient MG removal, this study was the first to prepare XSB-based high-performance activated carbon using KOH activation. Activated at temperatures between 600 and 800 °C, XSBAC-800 exhibited the highest specific surface area (1580 m/g) and pore volume (0.732 cm/g), leading to superior MG adsorption.
View Article and Find Full Text PDFWaste Manag
January 2025
School of Chemical Engineering, University of Birmingham, B15 2TT, Birmingham, UK.
Recycling waste to produce liquid fuels for the automotive and aviation industries is a major global concern, especially in light of the ongoing energy crisis. Because waste is used in thermal conversion processes, the resulting liquid products often require additional processing to reduce their density and viscosity, and to remove oxygenated compounds or pollutants that hinder further utilization. Catalytic hydrogenolytic reactions such as hydrodeoxygenation (HDO) and hydrocracking (HC) have been extensively applied to upgrade pyrolysis oils.
View Article and Find Full Text PDFACS Omega
January 2025
State Key Laboratory of Petroleum Resources and Engineering, China University of Petroleum, Beijing 102249, China.
Under the environment of energy transformation in the world, underground coal gasification (UCG) is an important means to realize the green and clean development and utilization of deep coal resources. Due to a series of complex chemical reactions, the porosity and permeability of coal have changed significantly. Accurately characterizing the porosity and permeability of gasified coal is of great significance to the field screening, production control, and numerical simulation of the UCG project.
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