Advanced microelectronics in the future may require semiconducting channel materials beyond silicon. Two-dimensional (2D) semiconductors, with their atomically thin thickness, hold great promise for future electronic devices. One challenge to achieving high-performance 2D semiconductor field effect transistors (FET) is the high contact resistance at the metal-semiconductor interface. In this study, we develop a charge-transfer doping strategy with WSe/α-RuCl heterostructures to achieve low-resistance ohmic contact for p-type monolayer WSe transistors. We show that hole doping as high as 3 × 10 cm can be achieved in the WSe/α-RuCl heterostructure due to its type-III band alignment, resulting in an ohmic contact with resistance of 4 kΩ μm. Based on that, we demonstrate p-type WSe transistors with an on-current of 35 μA·μm and an I/I ratio exceeding 10 at room temperature.

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http://dx.doi.org/10.1021/acs.nanolett.3c04195DOI Listing

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