Hydrogen (H) enrichment is a viable solution to deter the early blowout of oxy-fuel flames at high CO dilution levels and to enhance combustor turndown in the supercritical-CO cycles of zero-emission power plants. This was already implemented successfully in a previous study by the author, where H was premixed with the oxy-reactants upstream of the burner headend in a fully premixed flame stabilized on a micromixer-like burner. The micromixer technology is known for its superior flame stability and inherent fuel/oxidizer flexibility. To avoid the higher risk of flashback when H is premixed with the primary reactants, the present study introduces the enrichment H in a nonpremixed manner from the enhanced-blowout fuel circuit of the micromixer burner, which comprises circumferential jets that surround the core oxy-flame. This approach aims to enhance combustor turndown even further by benefiting from inducing stratification in the flame. It was found that the blowout limit of the fully premixed (CH/H/O/CO) flame did not improve by stratification (H-CH/O/CO); it deteriorated slightly. The present study thus analyzes the stability, morphology, and CO emissions of the stratified flame, in order to explain this behavior and provide recommendations for how hydrogen enrichment should be introduced in oxy-fuel micromixer combustors.
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http://dx.doi.org/10.1021/acsomega.3c08737 | DOI Listing |
Bot Stud
January 2025
Department of Life Sciences, National Chung Hsing University, Taichung, 40227, Taiwan.
Ice plant (Mesembryanthemum crystallinum L.) is a halophyte and an inducible CAM plant. Ice plant seedlings display moderate salt tolerance, with root growth unaffected by 200 mM NaCl treatments, though hypocotyl elongation is hindered in salt-stressed etiolated seedlings.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
College of Chemistry and Materials Science, The Key Laboratory of Functional Molecular Solids, Ministry of Education, The Key Laboratory of Electrochemical Clean Energy of Anhui Higher Education Institutes, Anhui Provincial Engineering Laboratory for New-Energy Vehicle Battery Energy-Storage Materials, Anhui Normal University, Jiuhua Road 189, Wuhu 241002, China.
Copper-based catalysts demonstrate distinctive multicarbon product activity in the CO electroreduction reaction (CORR); however, their low selectivity presents significant challenges for practical applications. Herein, we have developed a multilevel porous spherical CuO structure, wherein the mesopores are enriched with catalytic active sites and effectively stabilize Cu, while the macropores facilitate the formation of a "gas-liquid-solid" three-phase interface, thereby creating a microenvironment with an increasing water concentration gradient from the interior to the exterior. Potential-driven phase engineering and protonation synergistically optimize the reaction pathway, facilitating a switch between CO and CH.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
National Research and Development Center for Eel Processing Technology, Key Laboratory of Eel Aquaculture and Processing of Fujian Province, Fujian Provincial Engineering Research Center for Eel Processing Enterprise, Changle Juquan Food Co. Ltd., Fuzhou 350200, China.
Biofilms can increase bacterial resistance to antibiotic therapies. Edwardsiella tarda with biofilm is highly resistant to antibacterial treatment, especially for the antibiotic-resistant strain. In this study, we obtained biofilm-inhibiting aptamers against antibiotic-resistant E.
View Article and Find Full Text PDFIran J Pharm Res
June 2024
Department of Joint Surgery, Central Hospital Affiliated to Shandong First Medical University, Shandong, China.
Background: Femoral head necrosis (FHN) is a debilitating bone disease affecting an estimated 8 million people worldwide. Although specific drugs for FHN have limitations, targeted therapies have shown promising results. The significance of this study is underscored by the high prevalence of FHN, the limitations of current treatments, and the potential of targeted drugs and natural compounds for effective therapeutic interventions.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Chemistry, Faculty of Science, Cairo University, Cairo, Egypt.
This paper addresses the enhancement of formic acid electrooxidation (FAO) at Pt and Pt-NiOx nanoparticles based-catalysts assisted with urea derivatives as blending fuels. Blending formic acid with various ratios of urea derivatives showed noticeable enhancements of FAO as demonstrated by a favorable negative shift of its onset potential (E) and increase of its peak current density concurrently with suppression of the amount of CO poisoning reaction intermediate. Among all the used derivatives, phenyl urea (PU) showed superior enhancing effect towards the direct FAO with a minimal CO formation together with a favorable negative shift of E by 150 mV.
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