Achieving white-light emission, especially long-lived white circularly polarized luminescence, is challenging. Herein, chiral phosphorescent carbonized polymer dots (CPDs) have been prepared by using chiral polymer sodium alginate and chiral small molecule L-lysine as precursors. Benefiting from the efficient triplet-to-singlet phosphorescence resonance energy transfer (PRET), CPD-based long-lived warm white CPL has been achieved for the first time. This study provides a universal strategy for the convenient and efficient preparation of CPD-based long-lived white CPL materials.
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http://dx.doi.org/10.1039/d4cc00532e | DOI Listing |
EBioMedicine
December 2024
Vaccine Research Institute, Université Paris-Est Créteil, Faculté de Médecine, INSERM U955, Team 16, Créteil, France. Electronic address:
Background: Ideally, vaccination should induce protective long-lived humoral and cellular immunity. Current licensed COVID-19 mRNA vaccines focused on the spike (S) region induce neutralizing antibodies that rapidly wane.
Methods: Herein, we show that a subunit vaccine (CD40.
Phys Rev Lett
October 2024
CERN, Geneva, Switzerland.
Philos Trans R Soc Lond B Biol Sci
December 2024
Department of Anthropology and Archaeology, University of Calgary, Calgary, Alberta T2N 1N4, Canada.
Studying biological ageing in animal models can circumvent some of the confounds exhibited by studies of human ageing. Ageing research in non-human primates has provided invaluable insights into human lifespan and healthspan. Yet data on patterns of ageing from wild primates remain relatively scarce, centred around a few populations of catarrhine species.
View Article and Find Full Text PDFNat Commun
October 2024
Department of Biochemistry, University of Wisconsin-Madison, Madison, WI, USA.
ACS Appl Mater Interfaces
August 2024
Department of Chemistry, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, Republic of Korea.
A fluorescent dye, a dithiophene-conjugated benzothiazole derivative (), was prepared to have high fluorescence emission quantum yields (Φ) across various organic solvents. Its emission color modulation, from bright blue to deep red, was achieved through intramolecular charge transfer (ICT), acid-base equilibrium, and host-guest chemistry. Although it exhibits a weak solvatochromic effect, exhibited a bright fluorescence emission around 480 nm upon excitation at 390 nm in most solvents.
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