Phosphorus-doped nickel cobalt oxide (NiCoO) wrapped in 3D hierarchical hollow N-doped carbon nanoflowers as highly efficient bifunctional electrocatalysts for overall water splitting.

Properly design and fabricate capable electrocatalysts with 3D hierarchical hollow framework to realize cost-effective and efficacious overall water splitting (OWS) are particularly meaningful for the large-scale arrangement of pivotal energy technology. In this study, P-doped NiCoO nanoparticles encapsulated in N-doped carbon hierarchical hollow nanoflowers (P-NiCoO@NCHHNFs) were constructed using the hydrothermal-pyrolysis-phosphorization approach. This fascinating architecture can not merely serve as a conductive pathway for electron transfer, but at the same time effectively inhibited the aggregation and corrosion of the NiCoO nanoparticles. Additionally, the P doping not only regulates electronic structure configuration to boost the intrinsic activity of the catalyst, but also enhance electrochemical surface areas to reveal more accessible active sites. Attributing to these characteristics, the as-prepared P-NiCoO@NCHHNFs exhibit preeminent electrocatalytic performance with low overpotentials of 283 mV and 162 mV for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) (at 10 mA cm), respectively. Specifically, by using the P-NiCoO@NCHHNFs as bifunctional catalysts, a low potential of 1.56 V (at 10 mA cm) is sufficient to drive overall water splitting with splendid durability. This study proposed an innovative strategy for the conceiving and fabricating high-performance catalysts via heteroatom-doping.