Chemical and olfactometric inventory of gaseous spot vents in Mt. Amiata volcanic-geothermal area (Italy).

Geothermal areas are typically characterised by the presence of gases and odours in the background atmosphere, stemming from natural emissions and possible mining exploitation of the area. This study presents the first olfactometric investigation of endogenous gas emissions from natural and archaeo-industrial vents in a geothermal area. Mt. Amiata is known for its complex geology and historical cinnabar mining. This study offers an inventory of spot gas emissions, not only in terms of odour and chemical concentration but also including flux data, a ground-breaking achievement in this field. The primary challenge of this investigation was estimating the emitted flow from ground holes or mine entrances, posing the risk of hazardous anoxic conditions. To address this challenge, an innovative and adaptive approach was adopted. The main breakthrough method involved the adaptation of a balometer, typically employed for indoor ventilation systems, to measure the flow of endogenous gases. Field surveys revealed odour concentrations that can exceed 10 of ou/m, surpassing industrial emission level considerably. Chemical concentrations, primarily consisted of CO (80/90 %) and CH (∼10%), providing critical insights into the global warming potential (GWP) associated with natural emissions. Moreover, these spots, often located at ground level and lacking a substantial atmospheric dilution, pose potential risks to nearby individuals, with concentrations of gases such as HS surpassing safety thresholds. Total emissive flux of the investigated spot vents in the Mt. Amiata area, showed that the emission rate of HS is notably substantial (55 kg/h), roughly equivalent to emissions from approximately four 20 MW geothermal plants, as along with odour emission rates in the order of 10 ouE/s. Considering the GWP derived from emitted gases, the total inventory assessment of the spot vents resulted in 36 t/h or 23 t/h COeq, depending on the time horizon considered (GWP or GWP respectively).