The chemical reduction of group 1 metal cations to their zero-valent species is challenging. Now, a bipyridine-stabilized borate anion joins the ranks of suitable reducing agents and also proves active in the two-electron reduction of CO.
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http://dx.doi.org/10.1038/s42004-024-01171-w | DOI Listing |
ACS Appl Mater Interfaces
December 2024
School of Chemical Engineering, Sichuan University, Chengdu 610065, P. R. China.
To address the issues of infectious virus, bacterial secondary infections, skin pigmentation, and scarring caused by monkeypox virus (MPXV), a sprayable hydrogel with versatile functions was developed with comprehensive properties. Based on current research, the bioactive deep eutectic solvent (DES) of rosmarinic acid-proanthocyanidin-glycol (RPG) was designed and synthesized as active agent, and molecular docking was applied to discover its binding to MPXV proteins through H-bonds and van der Waals interactions, and the docking results show the binding energies between RA, PC, Gly and MPXV proteins are -58.7188, -50.
View Article and Find Full Text PDFACS Omega
December 2024
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, Henan 450001, P. R. China.
The development of conductive hydrogels has garnered significant attention in the field of wearable devices and smart sensors. However, the fabrication of hydrogels that possess both multifunctionality and structural stability remains a challenging task. In this study, a novel hydrogel, PHCB, was synthesized using a mild method and exhibited outstanding characteristics such as electrical conductivity, self-healing capability, antimicrobial activity, dimensional stability, and temperature sensitivity.
View Article and Find Full Text PDFChem Commun (Camb)
December 2024
Universidad Rey Juan Carlos, Departamento de Biología y Geología, Física y Química Inorgánica, Móstoles, 28933, Madrid, Spain.
Scorpionate ligands have emerged as pivotal components in the field of coordination chemistry and catalysis since the seminal work by Trofimenko in the late 1960s. These species have demonstrated an extraordinarily rich tridentate coordination chemistry, enhancing the stability of metal complexes. In addition, they offer the possibility of modifying the chemical and electronical features as κ-ligands, providing a wide variety of potential substrates with multiple donor atoms.
View Article and Find Full Text PDFInorg Chem
December 2024
Tianjin Key Laboratory of Functional Crystal Materials, Institute of Functional Crystal, Tianjin University of Technology, Tianjin 300384, China.
Heliyon
November 2024
Department of Physics, School of Physical Sciences, Federal University of Technology, Minna, Nigeria.
Ionizing radiation from natural and many synthetic sources is a remarkable tool in many scientific, production, quality control, food preservation, medical, security, and other technological processes. The need to protect humans (public and personnel), gadgets, the environment, and animals from the harmful effects of radiation, while maintaining and expanding the scope of application has made radiation protection an important topic to discuss. Among the methods and materials available for radiation control, shielding and the use of glass shields are the most effective and attractive methods and materials, respectively.
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