The prime goal of the present research is to synthesize pristine zinc sulfide (PZS) and cobalt (Co)-doped zinc sulfide (CDZS) thin films with different doping concentrations (DC) via chemical bath deposition (CBD) method. The effect of Co-doping on the surface topography, structural, optical and dc-electrical behaviors of PZS thin films has been ascertained. Scanning electron microscopy images exhibited nearly sphere-shaped agglomerates of grains dispersed throughout the surface with cracks in PZS thin film whereas cracks were absent in CDZS. Atomic force microscopy image displayed smooth surface of CDZS thin film with evenly dispersed small grains. The hexagonal wurtzite structure of PZS and CDZS thin films with varied X-ray diffraction (XRD) parameters was confirmed via XRD analysis. Optical investigation revealed that the optical direct band gap energy increased with decreasing DC from 12 % to 4 %. Alteration of other optical parameters namely absorption coefficient, extinction coefficient, refractive index, real and imaginary parts of dielectric constant, etc. with DC was also discussed. Direct current electrical investigation revealed that the current-voltage characteristics are linear for all thin films signifying that the electrical conduction in CDZS is ohmic in nature.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11036015 | PMC |
| http://dx.doi.org/10.1016/j.heliyon.2024.e29337 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Fabrication of high-performance tin halide perovskite thin-film transistors via chemical solution-based composition engineering.
Nat Protoc
January 2025
Department of Chemical Engineering, Pohang University of Science and Technology, Pohang, Gyeongbuk, Republic of Korea.
Metal halide perovskite semiconductors have attracted considerable attention because they enable the development of devices with exceptional optoelectronic and electronic properties via cost-effective and high-throughput chemical solution processes. However, challenges persist in the solution processing of perovskite films, including limited control over crystallization and the formation of defective deposits, leading to suboptimal device performance and reproducibility. Tin (Sn) halide perovskite holds promise for achieving high-performance thin-film transistors (TFTs) due to its intrinsic high hole mobility.
View Article and Find Full Text PDFFlexible micromachined ultrasound transducers (MUTs) for biomedical applications.
Microsyst Nanoeng
January 2025
Department of Electrical Engineering (ESAT-MNS), KU Leuven, Belgium.
The use of bulk piezoelectric transducer arrays in medical imaging is a well-established technology that operates based on thickness mode piezoelectric vibration. Meanwhile, advancements in fabrication techniques have led to the emergence of micromachined alternatives, namely, piezoelectric micromachined ultrasound transducer (PMUT) and capacitive micromachined ultrasound transducer (CMUT). These devices operate in flexural mode using piezoelectric thin films and electrostatic forces, respectively.
View Article and Find Full Text PDFCopper Tantalate by a Sodium-Driven Flux-Mediated Synthesis for Photoelectrochemical CO Reduction.
Small Methods
January 2025
Liquid Sunlight Alliance, Lawrence Berkeley National Laboratory, 1 Cyclotron Rd, Berkeley, CA, 94720, United States.
Copper-tantalate, CuTaO (CTO), shows significant promise as an efficient photocathode for multi-carbon compounds (C) production through photoelectrochemical (PEC) CO reduction, owing to its suitable energy bands and catalytic surface. However, synthesizing CTO poses a significant challenge due to its metastable nature and thermal instability. In this study, this challenge is addressed by employing a flux-mediated synthesis technique using a sodium-based flux to create sodium-doped CTO (Na-CTO) thin films, providing enhanced nucleation and stabilization for the CTO phase.
View Article and Find Full Text PDFRemote epitaxial crystalline perovskites for ultrahigh-resolution micro-LED displays.
Nat Nanotechnol
January 2025
Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, China.
The miniaturization of light-emitting diodes (LEDs) is pivotal in ultrahigh-resolution displays. Metal-halide perovskites promise efficient light emission, long-range carrier transport and scalable manufacturing for bright microscale LED (micro-LED) displays. However, thin-film perovskites with inhomogeneous spatial distribution of light emission and unstable surface under lithography are incompatible with the micro-LED devices.
View Article and Find Full Text PDFRefreshable memristor via dynamic allocation of ferro-ionic phase for neural reuse.
Nat Commun
January 2025
School of Optoelectronic Science and Engineering, University of Electronic Science and Technology of China, Chengdu, China.
Neural reuse can drive organisms to generalize knowledge across various tasks during learning. However, existing devices mostly focus on architectures rather than network functions, lacking the mimic capabilities of neural reuse. Here, we demonstrate a rational device designed based on ferroionic CuInPS, to accomplish the neural reuse function, enabled by dynamic allocation of the ferro-ionic phase.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!