Water purification using adsorption is a crucial process for maintaining human life and preserving the environment. Batch and dynamic adsorption modes are two types of water purification processes that are commonly used in various countries due to their simplicity and feasibility on an industrial scale. However, it is important to understand the advantages and limitations of these two adsorption modes in industrial applications. Also, the possibility of using batch mode in industrial scale was scrutinized, along with the necessity of using dynamic mode in such applications. In addition, the reasons for the necessity of performing batch adsorption studies before starting the treatment on an industrial scale were mentioned and discussed. In fact, this review article attempts to throw light on these subjects by comparing the biosorption efficiency of some metals on utilized biosorbents, using both batch and fixed-bed (column) adsorption modes. The comparison is based on the effectiveness of the two processes and the mechanisms involved in the treatment. Parameters such as biosorption capacity, percentage removal, and isotherm models for both batch and column (fixed bed) studies are compared. The article also explains thermodynamic and kinetic models for batch adsorption and discusses breakthrough evaluations in adsorptive column systems. The review highlights the benefits of using convenient batch-wise biosorption in lab-scale studies and the key advantages of column biosorption in industrial applications.
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http://dx.doi.org/10.1016/j.chemosphere.2024.142051 | DOI Listing |
Nanomaterials (Basel)
December 2024
Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China.
Cisplatin-based platinum compounds are important clinical chemotherapeutic agents that participate in most tumor chemotherapy regimens. Through density-functional theory calculations, the formation and stability of the inorganic oxide carrier, the mechanisms of the hydrolysis reaction of the activated platinum compound, and its binding mechanism with DNA bases can be studied. The higher the oxidation state of Pt (II to IV), the more electrons transfer from the magnesia-gold composite material to the platinum compound.
View Article and Find Full Text PDFLangmuir
December 2024
School of Physics, Zhejiang University, Hangzhou 310027, China.
The diffusion dynamics of polymer chains within a narrow slit formed by two patch-patterned surfaces is investigated utilizing Langevin dynamics simulations. These surfaces feature periodically arranged attractive patches of size and period , with a staggered configuration of (0.5, 0.
View Article and Find Full Text PDFACS Omega
December 2024
Physics Department, Laboratory of Biophysics and Nanosystems, Federal University of Maranhão, São Luís, MA 65085-580, Brazil.
Mayaro virus (MAYV) is an emerging mosquito-borne viral pathogen whose infection results in arthritogenic disease. Despite ongoing research efforts, MAYV biology is largely unknown. Physical virology can assess MAYV nanoparticle metastability, assembly/disassembly, and polymorphism, allowing us to understand virion architecture and dynamics.
View Article and Find Full Text PDFJ Chromatogr A
January 2025
SABIC Corporate Technology and Innovation, 1600 Industrial Boulevard, Sugar Land, TX 77478, United States. Electronic address:
The retention time of a polymer in liquid chromatography depends on the details of its microstructure and topology. Despite the number of separation modes and methods available for polymers, gaining quantitative information from chromatograms remains a challenge. A model able to predict the LC retention time of a polymer accounting for all possible variations in its microstructure could provide some valuable insight during method development and produce the information necessary to establish unambiguous structure/property relationships.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou, China.
Carbon atom has different bonding modes, which provides the possibility for the existence of multilayer carbon allotropes. Among these bonding modes, the sp hybrid bonding mode often causes atoms to be noncoplanar. This provides the possibility for the emergence of two-dimensional (2D) multilayer materials.
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