Integrating hydrogen with CNG is crucial for carbon neutrality and environmental goals, as it enhances flame temperature, reduces emissions, and combats global warming. This study employs the CHEMKIN tool to examine combustion characteristics, including adiabatic flame temperature, mole fraction, normalization, and production rate, in H-CNG mixtures under various atmospheric and operating conditions. Blending 50% hydrogen with CNG results in significant changes, including a temperature increase from 2322 to 2344 K when the hydrogen content is at 50%. The introduction of hydrogen causes a notable 30-35% reduction in CH mole fraction and a simultaneous 26.6% increase in C-normalized CH production. Free radicals play a role in affecting CO production, with the normalization of CO species increasing from 0.068 to 0.087. Through NSGA-II multi-objective optimization methods, the study identifies a 50% H-50% CNG blend as the optimal choice for thermal and environmental performance. The study explores the energy and environmental impacts of incorporating hydrogen into CNG-air combustion, with a specific focus on the effects of 50% H blending with CNG. Hydrogen blending benefits from elevated adiabatic flame temperature and increased free radical formation, ultimately leading to emission reduction. These findings firmly establish H-CNG mixtures as promising environmentally friendly alternatives with superior combustion characteristics. Their potential paves the way for significant progress towards achieving carbon neutrality and combating climate change through cleaner, more efficient fuel options.
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http://dx.doi.org/10.1007/s11356-024-33396-6 | DOI Listing |
Ecotoxicol Environ Saf
January 2025
Key Laboratory of Microbial Technology for Industrial Pollution Control of Zhejiang Province, College of Environment, Zhejiang University of Technology, Hangzhou, Zhejiang 310014, PR China.
Organophosphate flame retardants (OPFRs) are a class of substances that pose potential risks to human health and ecosystems due to their large-scale production, wide range of applications, and ubiquitous presence in the environment. With their potential for long-range atmospheric transport (LRAT), OPFR pollution in high-altitude areas has become an increasing concern. Herein, a general pretreatment method for OPFRs across various sample matrices was established and combined with gas chromatography-mass spectrometry (GC-MS), utilizing a programmed temperature ramp in the vaporization chamber to enable high-throughput detection of OPFRs in various environmental matrices.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
School of Management, Sichuan University of Science and Engineering, Zigong 643000, China.
In this work, the coprecipitation approach was successfully used to create Mg-Al hydrotalcite-like inhibitors modified with varying amounts of Zn, and their characteristics were assessed. The findings indicate that the flame retardancy of Mg-Al hydrotalcite (MgAl-LDHs) is not significantly affected by Zn content. By adding MgAl-LDHs, the temperature at which the exothermic reaction started to occur was raised from 146.
View Article and Find Full Text PDFJ Environ Manage
January 2025
Department of Forestry, College of Horticulture and Forestry, Huazhong Agricultural University, Wuhan, 430070, Hubei, China. Electronic address:
The readiness of leaf-litter to burn in the presence of fire differs greatly between species. Thus, forests composed of different species vary in their susceptibility to fire. Fire susceptibility of forests may also differ from the arithmetic means of flammability of their component species, i.
View Article and Find Full Text PDFNanomaterials (Basel)
December 2024
Institute for Energy and Materials Processes-Reactive Fluids, University of Duisburg-Essen, 47057 Duisburg, Germany.
Solid-state electrolytes for lithium-ion batteries, which enable a significant increase in storage capacity, are at the forefront of alternative energy storage systems due to their attractive properties such as wide electrochemical stability window, relatively superior contact stability against Li metal, inherently dendrite inhibition, and a wide range of temperature functionality. NASICON-type solid electrolytes are an exciting candidate within ceramic electrolytes due to their high ionic conductivity and low moisture sensitivity, making them a prime candidate for pure oxidic and hybrid ceramic-in-polymer composite electrolytes. Here, we report on producing pure and Y-doped Lithium Aluminum Titanium Phosphate (LATP) nanoparticles by spray-flame synthesis.
View Article and Find Full Text PDFMolecules
December 2024
Materia Nova Research Center, UMONS Innovation Center, Avenue Nicolas Copernic 3, B-7000 Mons, Belgium.
In this study, a sustainable cellulose-based flame-retardant additive was developed, characterized, and incorporated into polypropylene (PP). Microcrystalline cellulose (Cel) was chemically modified with PO using the solvent-free ball-milling mechanochemistry approach at room temperature. This modification enabled phosphorus grafting onto cellulose, significantly enhancing the cellulose charring ability and improving the thermal stability of the char as revealed by thermogravimetric analysis (TGA).
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