Molten salts are highly effective as a quenching medium for austempering and martempering processes, enabling precise control of cooling rates to achieve the desired microstructures and mechanical characteristics in steel components. One such promising molten salt is a multicomponent Ca (NO)-KNO molten salt. The current work explores the cooling severity of molten Ca (NO)-KNO mixtures, which are commonly used for such purposes. The said mixture, with varying concentrations and bath temperatures was used for quenching the Inconel probe with thermocouples. The temperature data extracted was used to determine the transient heat flux developed at the metal-quenchant interface. A set of critical points were assessed against the peak heat extraction rates. Additionally, the fluctuation of mean heat flux and surface temperature in relation to these crucial points were plotted, along with changes in composition and bath temperature of the quench media. The cooling intensity of these quench solutions, as measured by Inconel probes, correlated well with the average hardness values observed in steel probes. The level of homogeneity in heat transmission, as measured by the spatial variance of the normalized heat energy, decreased as the percentage of KNO in the quench medium increased.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11024971 | PMC |
http://dx.doi.org/10.1021/acsomega.3c10262 | DOI Listing |
Sci Rep
January 2025
Research Institute of Energy and Resources, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul, 08826, Republic of Korea.
To develop a direct production process for TiH powder from TiO, the reduction of TiO using Mg in molten MgCl - KCl salt under a high hydrogen chemical potential was investigated. The reduction of nano-sized TiO powder was conducted at 973 - 1073 K under an Ar or Ar and 10% H mixed gas atmosphere when the mass ratios of Mg to feed and salt to feed were 1.14 - 2.
View Article and Find Full Text PDFChem Commun (Camb)
January 2025
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 215123 Jiangsu, China.
A two-dimensional (2D) amorphous iridium cobalt oxide (Am-IrCoO) was prepared using the molten salt method. The optimal catalyst shows a low overpotential of 230 mV at 10 mA cm in 0.5 M HSO.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830, United States.
Molten salts are promising candidates in numerous clean energy applications, where knowledge of thermophysical properties and vapor pressure across their operating temperature ranges is critical for safe operations. Due to challenges in evaluating these properties using experimental methods, fast and scalable molecular simulations are essential to complement the experimental data. In this study, we developed machine learning interatomic potentials (MLIP) to study the AlCl molten salt across varied thermodynamic conditions ( = 473-613 K and = 2.
View Article and Find Full Text PDFEnviron Res
January 2025
MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, China.
In recent years, the accumulation of waste plastics and emergence plastic-derived pollutants such as microplastics have driven significantly the development and updating of waste plastic utilization technology. This study prepared the porous carbon (PC-1-KOH) material directly from polyethylene terephthalate (PET) in waste plastic bottles using KOH activation and molten salt strategy for efficient removal of antibiotic tetracycline (TC). The maximum removal efficiency of TC was 100.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!