AI Article Synopsis
- Tetraalkoxydiborons can be synthesized using acid-catalyzed reactions involving tetrahydroxydiboron or its anhydride with trialkyl orthoformates.
- The addition of diols to these mixtures results in high yields of diboron diolates.
- These methods provide a simpler and more efficient alternative to earlier synthesis techniques involving tetrakis(dimethylamino) diboron and tetrahydroxydiboron.
Article Abstract
Tetraalkoxydiborons can be easily prepared by acid-catalyzed reactions of tetrahydroxydiboron or its anhydride with trialkyl orthoformates. Addition of diols to these reaction mixtures afforded diboron diolates in high yield. In both cases, removal of volatile byproducts is all that is required for the isolation of the diboron. These methods constitute a convenient alternative to previous preparations from tetrakis (dimethylamino) diboron and tetrahydroxydiboron.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11077490 | PMC |
| http://dx.doi.org/10.1021/acs.joc.3c02992 | DOI Listing |
Publication Analysis
Top Keywords
diboron diolates
8
simple green
4
green preparation
4
preparation tetraalkoxydiborons
4
diboron
4
tetraalkoxydiborons diboron
4
diolates tetrahydroxydiboron
4
tetrahydroxydiboron tetraalkoxydiborons
4
tetraalkoxydiborons easily
4
easily prepared
4
Similar Publications
Simple and Green Preparation of Tetraalkoxydiborons and Diboron Diolates from Tetrahydroxydiboron.
J Org Chem
May 2024
Department of Chemistry, Michigan State University, 578 South Shaw Lane, East Lansing, Michigan 48824, United States.
Article Synopsis
- Tetraalkoxydiborons can be synthesized using acid-catalyzed reactions involving tetrahydroxydiboron or its anhydride with trialkyl orthoformates.
- The addition of diols to these mixtures results in high yields of diboron diolates.
- These methods provide a simpler and more efficient alternative to earlier synthesis techniques involving tetrakis(dimethylamino) diboron and tetrahydroxydiboron.
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!