Rechargeable lithium-sulfur (Li-S) batteries are promising for high-energy storage. However, conventional redox reactions involving sulfur (S) and lithium (Li) can lead to unstable intermediates. Over the past decade, many strategies have emerged to address this challenge, enabling nonconventional electrochemical reactions in Li-S batteries. In our Perspective, we provide a brief review of these strategies and highlight their potential benefits. Specifically, our group has pioneered a top-down approach, investigating Li-S reactions at molecular and subatomic levels, as demonstrated in our recent work on stable S isotopes. These insights not only enhance understanding of charge transfer and storage properties but also offer exciting opportunities for advancements in battery materials research.
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http://dx.doi.org/10.1021/acsami.4c03201 | DOI Listing |
Ultrasonics
January 2025
Department of Chemistry, University of Calicut, Calicut University (PO), Malappuram DT, Kerala - 673635, India. Electronic address:
Heliyon
August 2024
Department of Electrical, Mechanical and Industrial Engineering, Anhalt University of Applied Sciences, Köthen, 06366, Germany.
Nat Commun
August 2024
IAPP Dresden, Institute for Applied Physics, Technische Universität Dresden, Nöthnitzer Str. 61, 01187, Dresden, Germany.
Organic electrochemical transistors (OECTs) underpin a range of emerging technologies, from bioelectronics to neuromorphic computing, owing to their unique coupling of electronic and ionic charge carriers. In this context, various OECT systems exhibit significant hysteresis in their transfer curve, which is frequently leveraged to achieve non-volatility. Meanwhile, a general understanding of its physical origin is missing.
View Article and Find Full Text PDFMolecules
July 2024
Laboratoire de Chimie Analytique, de Physique Spatiale et Energétique (L@CAPSE), UFR/Sciences et Technologies (ST), Université Norbert ZONGO, Avenue Maurice Yameogo, Koudougou BP 376, Burkina Faso.
Deep eutectic solvents (DESs) are attracting considerable attention as non-conventional media for electrodeposition processes. This opinion contribution discusses the debated nature and definition of these solvents as well as some practical considerations of relevance when performing electrodeposition studies in DESs. Using a few illustrative case studies, it is shown that speciation is a key factor determining the electrochemical behaviour of chemical elements in different DESs, and that accounting for the speciation strong similarities can often be found with more conventional or more documented solvents.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, CAS Research/Education Center for Excellence in Molecular Sciences, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, China.
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