Nonconventional Electrochemical Reactions in Rechargeable Lithium-Sulfur Batteries.

ACS Appl Mater Interfaces

CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, CAS Research/Education Center for Excellence in Molecular Sciences, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100190, China.

Published: December 2024

AI Article Synopsis

  • Rechargeable lithium-sulfur (Li-S) batteries show promise for high-energy storage, but their conventional reactions often lead to unstable intermediates.
  • *Over the past decade, various strategies have been developed to improve the stability and efficiency of these batteries through nonconventional electrochemical reactions.
  • *Our research group has focused on a top-down approach, exploring reactions at molecular and subatomic levels, which has led to valuable insights and potential advancements in battery materials.

Article Abstract

Rechargeable lithium-sulfur (Li-S) batteries are promising for high-energy storage. However, conventional redox reactions involving sulfur (S) and lithium (Li) can lead to unstable intermediates. Over the past decade, many strategies have emerged to address this challenge, enabling nonconventional electrochemical reactions in Li-S batteries. In our Perspective, we provide a brief review of these strategies and highlight their potential benefits. Specifically, our group has pioneered a top-down approach, investigating Li-S reactions at molecular and subatomic levels, as demonstrated in our recent work on stable S isotopes. These insights not only enhance understanding of charge transfer and storage properties but also offer exciting opportunities for advancements in battery materials research.

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http://dx.doi.org/10.1021/acsami.4c03201DOI Listing

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