Three new distinct NIR α,α-NH-bridged BODIPY dimers were prepared by a direct nucleophilic substitution reaction. The synergistic effects of the nitrogen bridges and strong excitonic coupling between each BODIPY unit play major roles in enhancing the delocalization of an electron spin over the entire BODIPY dimers. The formed aminyl radical dimer showed an absorption maximum at 1040 nm.
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Org Lett
January 2025
DFG Cluster of Excellence livMatS @FIT, Institute of Organic Chemistry, Albertstraße 21, 79104 Freiburg (Breisgau), Germany.
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Langmuir
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