Correction for 'On the mercuration, palladation, transmetalation and direct auration of a C^N^C pincer ligand' by Alice Jane McEllin , , 2023, , 872-876, https://doi.org/10.1039/d2dt04114f.
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Correction: On the mercuration, palladation, transmetalation and direct auration of a C^N^C pincer ligand.
Dalton Trans
April 2024
Department of Chemistry, University of York, Heslington, YORK YO10 5DD, UK.
Correction for 'On the mercuration, palladation, transmetalation and direct auration of a C^N^C pincer ligand' by Alice Jane McEllin , , 2023, , 872-876, https://doi.org/10.1039/d2dt04114f.
View Article and Find Full Text PDFOn the mercuration, palladation, transmetalation and direct auration of a C^N^C pincer ligand.
Dalton Trans
January 2023
Department of Chemistry, University of York, Heslington, YORK YO10 5DD, UK.
The C^N^C ligand 2,6-bis(2,3-dialkoxyphenyl)pyridine forms dimercury and orthopalladated complexes, both of which may be transmetallated to gold(III) complexes; the gold complexes may also be formed directly in a Rh(III)-catalysed process, hence it is possible to circumvent the use of organomercury intermediates in the synthesis of this important class of compound.
View Article and Find Full Text PDFSelective palladation of a large (32 ring atom) macrocyclic ligand at a bis(N-heterocyclic carbene) coordination pocket through transmetallation of the corresponding mercury(II) derivative.
Dalton Trans
December 2012
School of Chemical Sciences, University of Auckland, Private Bag 92019, Auckland 1142, New Zealand.
Treatment of N(2),N(6)-bis(6-acrylamidopyridin-2-yl)pyridine-2,6-dicarboxamide with benzimidazole gives the acyclic aza-Michael addition product N(2),N(6)-bis(6-(3-(1H-benzo[d]imidazol-1-yl)propanamido)pyridin-2-yl)pyridine-2,6-dicarboxamide (2). The macrocycle N(1),N(7)-pyridine-2,6-dimethyl-N(2),N(6)-bis(6-(3-(1H-benzo[d]imidazol-1-yl)propanamido)pyridin-2-yl)pyridine-2,6-dicarboxamide dibromide ([H(2)L(2)]Br(2)) is formed through the double alkylation of 2 with 2,6-bis(bromomethyl)pyridine. The imidazole analogues of 2 and [H(2)L(2)]Br(2) (1 and [H(2)L(1)]Br(2), respectively) have also been prepared.
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