A PPhAu[B(CF)]-catalyzed reaction of enynals and alkenes for the construction of binaphthyl derivatives was described. This transformation was achieved through -Quinodimethane (-QDM) intermediate's extended conjugated addition process. The reaction has the advantages of wide substrate scopes, mild reaction conditions, high efficiency, and good scalability.
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| http://dx.doi.org/10.1021/acs.joc.4c00036 | DOI Listing |
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