The objective of this work was to study PAHs contamination in rice grains subjected to different milling types, after drying at different air temperatures in a direct-fired dryer and using firewood with different moisture contents as a heating source. In addition to verifying the persistence of these compounds after storage. Drying of rice grains was performed in a cross-flow dryer at air temperatures of 55 and 65 ºC. As heating source firewood containing different moisture contents was used. The presence of nine PAHs was detected. The drying air temperature, as well as the storage time, did not significantly influence the PAHs contamination of grains. The highest PAHs contamination was observed in grains from the brown subgroup. Grain polishing promoted a reduction in the PAH concentration. The grains subjected to parboilization showed a higher PAHs concentration. The use of firewood with higher moisture content promoted greater PAHs contamination in the grains.
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http://dx.doi.org/10.1007/s10068-023-01456-1 | DOI Listing |
Environ Sci Pollut Res Int
January 2025
Waste Science and Technology, Luleå University of Technology, Luleå, Sweden.
Improper management of wood impregnation chemicals and treated wood has led to soil contamination at many wood treatment sites, particularly with toxic substances like creosote oil and chromated copper arsenate (CCA). The simultaneous presence of these pollutants complicates the choice of soil remediation technologies, especially if they are to be applied in situ. In this laboratory study, we attempted to immobilise arsenic (As) and simultaneously degrade polycyclic aromatic hydrocarbons (PAHs) (constituents of creosote oil) by applying a modified electrochemical oxidation method.
View Article and Find Full Text PDFEnviron Sci Process Impacts
January 2025
Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education), School of Environmental Science and Technology, Dalian University of Technology, Dalian, 116024, China.
Environmentally persistent free radicals (EPFRs) have been widely detected in polycyclic aromatic hydrocarbon (PAH)-contaminated soils, but the activation of persulfate by inherent EPFRs in PAH-contaminated soil for the transformation of PAHs remains unclear. In the present study, benzo[]pyrene (B[]P) was selected as a representative PAH and its transformation in a persulfate/B[]P-contaminated soil system was studied without the addition of any other activator. Results indicated that EPFRs in the soil activated persulfate to produce reactive oxygen species (ROS) and degraded B[]P.
View Article and Find Full Text PDFToxicol Rep
June 2025
Department of Environmental Management and Toxicology, Dennis Osadabey University, Asaba, Delta State, Nigeria.
This study was conducted to evaluate the health risks related to eating crabs and periwinkles from Southern Nigerian coastal areas that are contaminated by crude oil. Periwinkles and crabs from contaminated locations were tested for Polycyclic aromatic hydrocarbon (PAH) and heavy metal (HM) levels using US-EPA standard, and the health risks to humans of eating these seafood were assessed. 20 samples of periwinkles and crabs were collected from crude oil-polluted coastal areas.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
Food Laboratory of Zhongyuan, Luohe, 462000, Henan Province, PR China.
Background: Edible oils are susceptible to contamination with polycyclic aromatic hydrocarbons (PAHs) throughout production, storage, and transportation processes due to their lipophilic nature. The necessity of quantifying PAHs present in complex oil matrices at trace levels, which bind strongly to impurities in oil matrices, poses a major challenge to the accurate quantification of these contaminants. Therefore, the development of straightforward and effective methods for the separation and enrichment of PAHs in oil samples prior to instrumental analysis is paramount to guaranteeing food safety.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and Health, Key Laboratory of Environmental Catalysis and Health Risk Control, Institute of Environmental Health and Pollution Control, Guangdong University of Technology, Guangzhou 510006, China; Guangzhou Key Laboratory of Environmental Catalysis and Pollution Control, Guangdong Basic Research Center of Excellence for Ecological Security and Green Development, School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou 510006, China. Electronic address:
Long-term occupational exposure to metals and organics have been reported to be under great health risks. However, limited data are available on the molecular mechanism between combined exposure to metals and polycyclic aromatic hydrocarbons (PAHs) and harmful health effects. In present work, non-target metabolomics study was conducted based on urine samples from nonferrous metal smelting workers (n = 207), surrounding residents (n = 180), and the control residents (n = 187) by using ultra-high-performance liquid chromatography coupled with quadrupole time-of-flight mass spectrometry (UHPLC-QTOF-MS).
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