We study the nontrivial thermodynamic responses of an overdamped Brownian system driven by an unbiased driving force when the particle is confined inside a bilobal irregular structure. The spatial irregularity of the confinement results in an effective entropic bistable potential along the direction of transport. We calculate the thermodynamic response functions in terms of the averaged work done and the absorbed heat over a cycle of driving. We find that the thermodynamic responses are influenced by the nonlinearity of the effective entropic potential, the frequency of the external periodic driving force, and the random thermal fluctuations in a nontrivial way. In the presence of an optimal amount of thermal noise and a favoring driving frequency, the process exhibits a resonance-like precedent in terms of both output work and absorbed heat. We explore the conditions to get best synchronized work extraction (or absorbed heat), which can be utilized as a potential quantifier of an entropic stochastic resonance phenomenon. Finally, we identify a hallmark of entropy dominance over an analogous energy-driven scenario in terms of output work.
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http://dx.doi.org/10.1021/acs.jpcb.3c08066 | DOI Listing |
Photo-thermal catalysis represents a promising strategy to improve the sustainability of chemical transformations by integrating light and heat into a single process. However, materials featuring excellent harvesting and utilization of solar energy are still needed. Here, we report a photo-thermal catalyst architecture based on carbon-coated urchin-like silica nanospheres (KCC-1) decorated with Ru nanoparticles that maximizes light absorption and heat confinement.
View Article and Find Full Text PDFThe EFSA Panel on Food Additive and Flavourings (FAF Panel) provides a scientific opinion on the safety assessment of the proposed use of pea fibre concentrate (FIPEA) as a food additive. FIPEA is a powder consisting mainly of dietary fibres (i.e.
View Article and Find Full Text PDFSmall
March 2025
Key Laboratory of Biorheological Science and Technology, Ministry of Education, College of Bioengineering, Chongqing University, No. 174 Shazheng Road, Chongqing, 400044, China.
The dynamic process in tumor ablation requires both the generation of reactive oxygen species (ROS) to elicit immunogenic cell death (ICD) and the subsequent reduction of ROS levels to maintain the stimulatory activity of signaling proteins and recover T cells' immune function. Inspired by the regulation mechanism of redox homeostasis in myeloid-derived suppressor cells and the high-selectivity in alcohols/aldehydes conversions of 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) and Fe(III) synergistic catalysis, photoenzymatic modulators with contradictory but synergistic functions are developed for adaptive photo-immunotherapy of cancer. In particular, poly(caffeic acid) (PCA) nanospheres are synthesized by highly efficient oxidative polymerization of CA.
View Article and Find Full Text PDFPlant J
March 2025
National Institute of Plant Genome Research, Aruna Asaf Ali Marg, New Delhi, 110067, India.
Plant flavonols act primarily as ultraviolet radiation absorbers, reactive oxygen species scavengers, and phytoalexins, and they contribute to biotic and abiotic stress tolerance in plants. Banana (Musa acuminata), an herbaceous monocot and important fruit crop, accumulates flavonol derivatives in different organs, including the edible fruit pulp. Although flavonol content varies greatly in different organs, the molecular mechanisms involving transcriptional regulation of flavonol synthesis in banana are not known.
View Article and Find Full Text PDFMol Pharm
March 2025
Department of Chemistry and Biochemistry, The University of Texas at Dallas, 800 West Campbell Road, Richardson, Texas 75080, United States.
Photothermal therapy (PTT) uses near-infrared (NIR) light and a photothermal agent (PTA) to generate heat to kill tumor cells. PTT is an attractive therapy for highly metastatic tumors─such as triple-negative breast cancer (TNBC)─because PTT is a potent activator of immunogenic cell death (ICD). ICD is characterized by the production of damage-associated molecular patterns (DAMPs) that help the immune system recognize cancer cells as "nonself.
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