Unveiling activation mechanism of persulfate by homologous hemp-derived biochar catalysts for enhanced tetracycline wastewater remediation.

Bioresour Technol

Key Laboratory for Biobased Materials and Energy of Ministry of Education, Guangdong Laboratory for Lingnan Modern Agriculture, College of Materials and Energy, South China Agricultural University, Guangzhou 510643, China. Electronic address:

Published: May 2024

AI Article Synopsis

  • Advancements in biochar for activating persulfate (PS) processes show promise for treating wastewater, particularly focused on tetracycline (TC) contamination.
  • The study compares two types of biochar—regular (BC) and nitrogen-doped (NBC)—highlighting that NBC changes the activation mechanism of PS, impacting treatment effectiveness.
  • The BC-PS system mainly uses a radical pathway for pollutant removal, while the NBC-PS system utilizes a stable non-radical pathway, demonstrating better performance and resistance to interference in organic wastewater treatment.

Article Abstract

Advancements in biochar activating persulfate advanced oxidation processes (PS-AOP), have gained significant attention. However, the understanding of biochar-based catalysts in activating PS remains limited. Herein, biochar (BC) and N-doped biochar (NBC) were synthesized from hemp for activating PS to treat tetracycline (TC) wastewater and analyzed their mechanisms separately. Surprisingly, N-doped in biochar leads to a change in the activation mechanism of PS. The BC-PS system operates mainly through a radical pathway, advantageous for treating soil organic pollution (68%) with pH adaptability (less than 10% variation). Nevertheless, the NBC-PS system primarily employs an electron transfer non-radical pathway, demonstrating stability (only 7% performance degradation over four cycles) and enhanced resistance to anionic interference (less than 10% variation) in organic wastewater treatment. This study provides a technical reference and theoretical foundation for enhancing biochar activation of PS in the removal of organic pollutants from aquatic and terrestrial environments.

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Source
http://dx.doi.org/10.1016/j.biortech.2024.130684DOI Listing

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