Because of its unique molecular structure and renewable properties, vegetable oil has gradually become the focus of researchers. In this work, castor oil was first transformed into a castor oil-based triacrylate structure (MACOG) using two steps of chemical modification, then it was prepared into castor oil-based waterborne polyurethane acrylate emulsion, and finally, a series of coating materials were prepared under UV curing. The results showed that with the increase in MACOG content, the glass transition temperature of the sample was increased from 20.3 °C to 46.6 °C, and the water contact angle of its surface was increased from 73.85 °C to 90.57 °C. In addition, the thermal decomposition temperature, mechanical strength, and water resistance of the samples were also greatly improved. This study not only provides a new idea for the preparation of waterborne polyurethane coatings with excellent comprehensive properties but also expands the application of biomass material castor oil in the field of coating.
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http://dx.doi.org/10.3390/polym16070949 | DOI Listing |
Polymers (Basel)
November 2024
Hubei Key Laboratory of Purification and Application of Plant Anti-Cancer Active Ingredients, College of Chemistry and Life Sciences, Hubei University of Education, Wuhan 430205, China.
Eco-friendly castor oil-based composites with a high content of clam shell powder were prepared in this study. Biomass composites were prepared by blending castor-oil-based polyurethane prepolymer (COPU) with a filler consisting of high-content clam shell powder (CSP), named CSP-COPU. The structure, microstructure, mechanical properties, and thermal stability of the composites were investigated.
View Article and Find Full Text PDFACS Omega
December 2024
Chemical Engineering Department, Istanbul Technical University, Istanbul, 34469, Turkey.
The current study focuses on investigating the potential of produced graphene oxide (GO)/oil-based polyurethane composite films as a drug carrier for 5-fluorouracil (5-FU). Polyurethane was synthesized starting from blends of castor oil and sunflower oil-based glyceride, followed by GO and 5-FU anticancer drug bearing film production by solution casting. GO/PU composite film samples were characterized by FTIR, TGA and SEM analysis, confirming the PU production and distribution of 5-FU drug at a homogeneous level in GO/PU films.
View Article and Find Full Text PDFBiomacromolecules
November 2024
Polymer Science & Technology Unit, Advanced Materials Laboratory, CSIR-Central Leather Research Institute (CSIR-CLRI) Sardar Patel Road, Adyar, Chennai 600 020, India.
Hydrogels are indispensable for a variety of applications. Conventional biomaterial-based hydrogels, typically made from proteins or polysaccharides, often suffer from high costs, poor mechanical properties, and limited chemical functionality for modification. In this work, we present a novel hydrogel developed from modified castor oil, which is a renewable and cost-effective resource.
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October 2024
Colloids and Polymers Research Group School of Chemical Engineering, Vellore Institute of Technology, Vellore 632014, India.
This paper proposes a new class of novel 2D layered structured materials, such as MXene (MX), for the synthesis of innovative nanofluids as coolants to evaluate the convective heat transfer performance of a double-pipe heat exchanger (DPHE). Convective heat transfer experiments were successfully conducted in lab-scale fabricated DPHE using low-concentration MXene nanofluids by varying the volume concentration of MXene nanoparticles (0.01-0.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
October 2024
Faculty of Engineering, Pharos University in Alexandria, PO Box 37, Sidi Gaber, Alexandria, Egypt.
In order to combat environmental pollution and the depletion of non-renewable fuels, feasible, eco-friendly, and sustainable biodiesel production from non-edible oil crops must be augmented. This study is the first to intensify biodiesel production from castor oil using a self-manufactured cylindrical stator-rotor hydrodynamic cavitation reactor. In order to model and optimize the biodiesel yield, a response surface methodology based on a 1/2 fraction-three-level face center composite design of three levels and five experimental factors was used.
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