A Novel Polyfunctional Polyurethane Acrylate Derived from Castor Oil-Based Polyols for Waterborne UV-Curable Coating Application.

Polymers (Basel)

Key Laboratory for Biobased Materials and Energy of Ministry of Education, College of Materials and Energy, South China Agricultural University, Guangzhou 510642, China.

Published: March 2024

AI Article Synopsis

  • Vegetable oil, particularly castor oil, is gaining research attention due to its renewable properties and unique molecular structure.
  • Through a two-step chemical modification process, castor oil was converted into a triacrylate structure and subsequently used to create a waterborne polyurethane acrylate emulsion that undergoes UV curing.
  • The study demonstrated that increasing the MACOG content improved the thermal and mechanical properties of the coatings, highlighting potential advancements in the use of castor oil for high-performance coating applications.

Article Abstract

Because of its unique molecular structure and renewable properties, vegetable oil has gradually become the focus of researchers. In this work, castor oil was first transformed into a castor oil-based triacrylate structure (MACOG) using two steps of chemical modification, then it was prepared into castor oil-based waterborne polyurethane acrylate emulsion, and finally, a series of coating materials were prepared under UV curing. The results showed that with the increase in MACOG content, the glass transition temperature of the sample was increased from 20.3 °C to 46.6 °C, and the water contact angle of its surface was increased from 73.85 °C to 90.57 °C. In addition, the thermal decomposition temperature, mechanical strength, and water resistance of the samples were also greatly improved. This study not only provides a new idea for the preparation of waterborne polyurethane coatings with excellent comprehensive properties but also expands the application of biomass material castor oil in the field of coating.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC11013653PMC
http://dx.doi.org/10.3390/polym16070949DOI Listing

Publication Analysis

Top Keywords

castor oil-based
12
polyurethane acrylate
8
castor oil
8
waterborne polyurethane
8
castor
5
novel polyfunctional
4
polyfunctional polyurethane
4
acrylate derived
4
derived castor
4
oil-based polyols
4

Similar Publications

Eco-Friendly Castor Oil-Based Composite with High Clam Shell Powder Content.

Polymers (Basel)

November 2024

Hubei Key Laboratory of Purification and Application of Plant Anti-Cancer Active Ingredients, College of Chemistry and Life Sciences, Hubei University of Education, Wuhan 430205, China.

Eco-friendly castor oil-based composites with a high content of clam shell powder were prepared in this study. Biomass composites were prepared by blending castor-oil-based polyurethane prepolymer (COPU) with a filler consisting of high-content clam shell powder (CSP), named CSP-COPU. The structure, microstructure, mechanical properties, and thermal stability of the composites were investigated.

View Article and Find Full Text PDF

The current study focuses on investigating the potential of produced graphene oxide (GO)/oil-based polyurethane composite films as a drug carrier for 5-fluorouracil (5-FU). Polyurethane was synthesized starting from blends of castor oil and sunflower oil-based glyceride, followed by GO and 5-FU anticancer drug bearing film production by solution casting. GO/PU composite film samples were characterized by FTIR, TGA and SEM analysis, confirming the PU production and distribution of 5-FU drug at a homogeneous level in GO/PU films.

View Article and Find Full Text PDF

Hydrogels are indispensable for a variety of applications. Conventional biomaterial-based hydrogels, typically made from proteins or polysaccharides, often suffer from high costs, poor mechanical properties, and limited chemical functionality for modification. In this work, we present a novel hydrogel developed from modified castor oil, which is a renewable and cost-effective resource.

View Article and Find Full Text PDF

This paper proposes a new class of novel 2D layered structured materials, such as MXene (MX), for the synthesis of innovative nanofluids as coolants to evaluate the convective heat transfer performance of a double-pipe heat exchanger (DPHE). Convective heat transfer experiments were successfully conducted in lab-scale fabricated DPHE using low-concentration MXene nanofluids by varying the volume concentration of MXene nanoparticles (0.01-0.

View Article and Find Full Text PDF

In order to combat environmental pollution and the depletion of non-renewable fuels, feasible, eco-friendly, and sustainable biodiesel production from non-edible oil crops must be augmented. This study is the first to intensify biodiesel production from castor oil using a self-manufactured cylindrical stator-rotor hydrodynamic cavitation reactor. In order to model and optimize the biodiesel yield, a response surface methodology based on a 1/2 fraction-three-level face center composite design of three levels and five experimental factors was used.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!