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Hyper-Cross-Linked Polymer-Derived Carbon-Coated Fe-Ni Alloy/CNT as a Bifunctional Electrocatalyst for Rechargeable Zinc-Air Batteries.
J Phys Chem Lett
January 2025
Department of Physics, Indian Institute of Technology Delhi (IITD), Delhi 110016, India.
The oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are considered to be the most important processes in metal-air batteries and regenerative fuel cell devices. Metal-organic polymers are attracting interest as promising precursors of advanced metal/carbon electrocatalysts because of their hierarchical porous structure along with the integrated metal-carbon framework. We developed carbon-coated CNTs with Ni/Fe and Cu/Fe as active sites.
View Article and Find Full Text PDFCoordinated human-exoskeleton locomotion emerges from regulating virtual energy.
PLoS One
January 2025
Department of Mechanical and Mechatronics Engineering, University of Waterloo, Waterloo, ON, Canada.
Lower-limb exoskeletons have demonstrated great potential for gait rehabilitation in individuals with motor impairments; however, maintaining human-exoskeleton coordination remains a challenge. The coordination problem, referred to as any mismatch or asynchrony between the user's intended trajectories and exoskeleton desired trajectories, leads to sub-optimal gait performance, particularly for individuals with residual motor ability. Here, we investigate the virtual energy regulator (VER)'s ability to generate coordinated locomotion in lower limb exoskeleton.
View Article and Find Full Text PDFHeteroarene-Fused Benzo[b]arsoles: Structure, Photophysical Properties, and Effects of the Bridging Element.
Chem Asian J
January 2025
Kyoto Institute of Technology: Kyoto Kogei Sen'i Daigaku, Faculty of Molecular Chemistry and Engineering, Goshokaido-cho, Matsugasaki, Sakyo-ku, 606-0962, Kyoto, JAPAN.
Heteroarene-fused heteroles have attracted considerable attention owing to their unique electronic and photophysical properties. The bridging element plays a crucial role in determining the electronic characteristics of the resulting π-conjugated molecules. In this study, we synthesized a series of heteroarene-fused benzo[b]arsoles and investigated their structures and photophysical properties.
View Article and Find Full Text PDFInsights into the adsorption mechanisms of VOCs molecules on non-oxidized and oxidized SnO (110) monolayer: DFT analysis.
J Mol Model
January 2025
Laboratory of Nanostructures and Advanced Materials, Mechanics and Thermofluids, Faculty of Sciences and Technologies, Hassan II University of Casablanca, B.P 146, 20650, Mohammedia, Morocco.
Context: Designing efficient sensitive materials for the detection of volatile organic compounds (VOCs) such as ethanol, acetone, and benzene is stringent owing to the significant environmental and health risks induced by these compounds, in addition to their role as biomarkers for chronic diseases and food quality. This study investigates the adsorption mechanisms of VOC molecules (ethanol, acetone, and benzene) on both non-oxidized and oxidized SnO (110) monolayers and identifies the most suitable surface for gas sensing applications. For this, we examined structural properties, adsorption energies, density of states, gas responses, and recovery times.
View Article and Find Full Text PDFCollagen Alpha 1(XI) Amino-Terminal Domain Modulates Type I Collagen Fibril Assembly.
Biochemistry
January 2025
Biomolecular Research Institute, Boise State University, 1910 University Drive, Boise, Idaho 83725, United States.
The amino-terminal domain of collagen α1(XI) plays a key role in controlling fibrillogenesis. However, the specific mechanisms through which various isoforms of collagen α1(XI) regulate this process are not fully understood. We measured the kinetics of collagen type I self-assembly in the presence of specific collagen α1(XI) isoforms.
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