Morphology does not matter: WSe luminescence nanothermometry unravelled.

Nanoscale

Departamento de Química Física, Facultad de Ciencias, Universidad de Cádiz, E-11510 Puerto Real, Cádiz, Spain.

Published: May 2024

Transition metal dichalcogenides, including WSe, have gained significant attention as promising nanomaterials for various applications due to their unique properties. In this study, we explore the temperature-dependent photoluminescent properties of WSe nanomaterials to investigate their potential as luminescent nanothermometers. We compare the performance of WSe quantum dots and nanorods synthesized using sonication synthesis and hot injection methods. Our results show a distinct temperature dependence of the photoluminescence, and conventional ratiometric luminescence thermometry demonstrates comparable relative thermal sensitivity (0.68-0.80% K) and temperature uncertainty (1.3-1.5 K), irrespective of the morphology of the nanomaterials. By applying multiple linear regression to WSe quantum dots, we achieve enhanced thermal sensitivity (30% K) and reduced temperature uncertainty (0.1 K), highlighting the potential of WSe as a versatile nanothermometer for microfluidics, nanofluidics, and biomedical assays.

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Source
http://dx.doi.org/10.1039/d4nr00014eDOI Listing

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